![]() | |
![]() | |
Identifiers | |
---|---|
3D model (JSmol)
|
|
ChemSpider | |
PubChem CID
|
|
UNII | |
CompTox Dashboard (EPA)
|
|
| |
| |
Properties | |
NH4CN | |
Molar mass | 44.0559 g/mol |
Appearance | colourless crystalline solid |
Density | 1.02 g/cm3 |
Melting point | 36 °C (decomp.) |
very soluble | |
Solubility | very soluble in alcohol |
Structure | |
cubic | |
Related compounds | |
Other anions
|
Ammonium hydroxide Ammonium azide Ammonium nitrate |
Other cations
|
Sodium cyanide Potassium cyanide |
Related compounds
|
Ammonia Hydrogen cyanide |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
|
Ammonium cyanide is an unstable inorganic compound with the formula NH4CN.
Ammonium cyanide is generally used in organic synthesis.[citation needed] Being unstable, it is not shipped or sold commercially.
Ammonium cyanide is prepared by combining solutions of hydrogen cyanide and ammonia:[citation needed]
It may be prepared by the reaction of calcium cyanide and ammonium carbonate:[citation needed]
In dry state, ammonium cyanide is made by heating a mixture of potassium cyanide or potassium ferrocyanide with ammonium chloride and condensing the vapours into ammonium cyanide crystals:[citation needed]
Ammonium cyanide decomposes to ammonia and hydrogen cyanide, often forming a black polymer of hydrogen cyanide:[1]
It undergoes salt metathesis reaction in solution with a number of metal salts to form metal–cyanide complexes.
Reaction with ketones and aldehydes yield aminonitriles, as in the first step of the Strecker amino acid synthesis:
Further information: Cyanide poisoning |
Ammonium cyanide is highly toxic.