Pallasites
— Class —
A slice of the Esquel pallasite, clearly showing the large olivine crystals suspended in the metal matrix.
TypeStony-iron
Subgroups
CompositionMeteoric iron, Silicates
Total known specimens49 Main group, 5 Eagle Station, 2 Pyroxene grouplet, 38 ungrouped (93 total)

The pallasites are a class of stony–iron meteorite. They are relatively rare, and can be distinguished by the presence of large olivine crystal inclusions in the ferro-nickel matrix.

These crystals represent mantle and core material from differentiated planetesimals, which were destroyed by violent collisions during the early formation of the Solar System.

Structure and composition

It consists of centimetre-sized olivine crystals of peridot quality in an iron-nickel matrix. Coarser metal areas develop Widmanstätten patterns upon etching. Minor constituents are schreibersite, troilite, chromite, pyroxenes, and phosphates (whitlockite, stanfieldite, farringtonite, and merrillite).[1][2]

Classification and subgroups

Eagle Station, ES group

Using the oxygen isotopic composition, meteoric iron composition and silicate composition pallasites are divided into 4 subgroups:[3][4]

Origin

Pallasites were once thought to originate at the core-mantle boundary of differentiated asteroids that were subsequently shattered through impacts. An alternative recent hypothesis is that they are impact-generated mixtures of core and mantle materials. This hypothesis is supported by isotopic analysis indicating admixture of material from multiple planetesimals.[5] [6]

History

Krasnojarsk meteorite

A common error is to associate their name with the asteroid 2 Pallas but their actual name is after the German naturalist Peter Pallas (1741–1811), who studied in 1772 a specimen found earlier near Krasnoyarsk in the mountains of Siberia that had a mass of 680 kilograms (1,500 lb).[a] The Krasnoyarsk mass described by Pallas in 1776 was one of the examples used by E.F.F. Chladni in the 1790s to demonstrate the reality of meteorite falls on the Earth, which most scientists at his time considered as fairytales. This rock mass was dissimilar to all rocks or ores found in this area (and the large piece could not have been accidentally transported to the find site), but its content of native metal was similar to other finds known from completely different areas.[7][8]

Pallasite falls

Pallasites are a rare type of meteorite. Only 61 are known to date, including 10 from Antarctica, with four being observed falls.[9][10] The following four falls are in chronological order:

Notable pallasite finds

Brenham
Imilac full slice

Although pallasites are a rare meteorite type, enough pallasite material is found in museums and meteorite collections and is available for research. This is due to several large finds, some of which yielded more than a metric ton. The following are the largest finds:

Notes

  1. ^ Peter Pallas' account of the meteorite near Krasnoyarsk appears in:
    • Pallas, P.S. (1778). Reise durch verschiedene Provinzen des russischen Reichs in einem ausführlichen Auszuge, dritte Teil [Journey through various provinces of the Russian Empire, in an extensive excerpt, 3rd part] (in German). Frankfurt and Leipzig, (Germany): Johann Georg Fleischer. pp. 315–325.
    During his journey through Russia, in the vicinity of Krasnoyarsk, Pallas learned of a huge meteorite. From p. 315: "Die vorzüglichste Merkwürdigkeit aus dem Mineralreiche, welche ich in der Krasnojarkische Gegend ausfindig gemacht habe, ist einen ungeheure fast vierzig Pud oder 1600 Pfund schwere Masse von drusigt gewachsenem gediegnen Eisen, worüber etwas umständlicher geredet werden muß." (The most outstanding oddity in the mineral realm, which I located in the vicinity of Krasnoyarsk, is a huge, almost 40 pood or 1600 funt [i.e., 655 kg / 1444 pound] mass of native iron [that had] become pitted by weathering, about which something must be said at some length.)

    Pallas was informed about the meteorite by the chief foreman of a local mine, Johann Casper Mettich, who had been directed to the meteor by Jacob Medvedef of Ubeiskaya, a local blacksmith and former Cossack. Mettich had been sent to find the meteor in order to obtain a sample and thus determine whether it contained any precious metals. Mettich described its appearance. From p. 317: " … einen scheinbarlich über dreysig Pud schweren Eisen-Kriz, welcher voll gelber sproder Steinchen, von der Grösse einer Zeder-Nuß saß, die man nicht ganz herausklopfen konnte. Dieses und der Klang des Krizes kam mir merkwürdig vor." ( … a block [i.e., bloom ] of iron obviously [weighing] over 30 pood, which was full of brittle, yellow, little stones, the size of pine nuts, which couldn't be knocked out whole. This and the ringing tone [that the meteorite made when it was struck] seemed strange to me.) Mettich said that Medvedef later removed the meteor to an unknown location.

    On p. 318, Medvedef said of the meteorite: "Weil die besondre Schmeidigkeit und Weisse des Eisens in der Masse, und deren klingender Ton ihn argwöhnisch machte, daß es wohl etwas edleres als Eisen seyn könnte, auch die Tartaren, welche diese Eisenwake als ein vom Himmel gefallenes Heiligthum betracteten, ihn in dieser Meynung bestärkten, … " (Because of the especial malleability and whiteness of the iron, and [because] of the ringing tone [that it made when struck], [it] made him suspicious that it could perhaps be somewhat more noble than iron [i.e., might contain precious metals]; also the Tartars, who regarded this iron boulder as a sacred relic [which had] fallen from the sky, strengthened him in this opinion, … ) Medvedef said that he had moved the stone to his village of Malayaderevna or Medvedeva, outside Ubeiskaya. Pallas said (p. 318) that in the mail of November 1771, he had received a piece of the meteorite from a Tartar soldier, who had found the meteorite on Medvedef's farm and had (with some difficulty) chiseled some samples off the meteorite. Pallas immediately had the soldier haul the meteorite 220 versts (i.e., 235 km / 146 miles) into the city of Krasnoyarsk.

    Pallas then (pp. 319–321) described the meteorite in detail. "Die ganze Wake scheint eine rohe eisenteinartige Schwarte gehabt zu haben, die auf einem gross Theil der Oberfläche durch die Hammerschläge, womit man Stücken davon abzusondern gesucht hat, verloren gegangen ist. Ausser dieser ziemlich dünnen Rinde ist das ganze innere Wesen derselben ein geschmeidiges weißbrüchiges, wie ein grober Seeschwam löcherigt ausgewebtes Eisen, dessen Zwischenräume mit runden und länglichten Tropfen eines sehr spröden aber harten Bernsteingelben vollkommen hellen und reinen Glases oder Hyacinthenflusses genau ausgefüllt sind. Diese Tropfen haben verschiedne länglich runde Gestalten und eine sehr glatte Oberfläche, die mehrentheils eine, zwey, auch wohl drey ganz platte Seiten an dem stumpfen Theil ihres sonst abgerundeten und mit andern Tropfen oft zusammenfliessenden Cörpers zeigen. Diese Textur und diese Flußtropfen, welche die Grösse vom Hanfkorn bis zur grossen Erbse oder drüber und bald eine reine gelbe, bald eine gelb-braune oder auf grünlich spielende Farbe haben, zeigen sich durch die ganze Masse einförming und ohne alle Spur von Schlacken oder künstlichem Feuer. Das Eisen ist so zähe daß drey bis vier Schmiede oft ganze Vormittage gearbeitet haben, um mit stählernen Keilen und Schmiedehämmern eine oder die andre Ecke von der Masse abzustuffen, die doch gemeiniglich nur zu einigen Pfunden gewonnen werden konnten, … " (The whole boulder seems to have had a rough skin like iron ore, which, on a large part of the surface, had gone missing as a result of hammer blows with which one sought to detach pieces from it. Besides this rather thin rind, the whole internal character of it is a malleable, brittle, white, lacy iron, holey like a coarse sea sponge, whose interstices are quite filled with round and oblong drops of a very brittle but hard amber-yellow, completely clear and pure glass or "hyacinth flux" [i.e., a yellow-green form of fluorite]. These drops have various elongated forms and a very smooth surface, which to a large extent show one, two, and even three quite flat sides at the blunt part of their otherwise rounded bodies, which often coalesce with other drops. This texture and these drops of flux [or: fluorite], which [vary in] size from hemp seeds to large peas or larger and have now a pure yellow, now a yellow-brown or green-flecked color, appear uniform throughout the whole mass and without any trace of slag or man-made fire. The iron is so tough that 3–4 smiths often worked whole mornings in order to break off one or another corner of the mass with steel wedges and blacksmith's hammers, [but] could generally obtain only a few pounds [of sample material from the meteorite], … )

    The German-Russian scientist Friedemann Adolph Goebel (1826–1895) reviewed Pallas' account, adding some details to it: English translations of some relevant passages from Pallas' Reise appear in:

References

  1. ^ Buseck, P.R. (1977). "Pallasite meteorites: mineralogy, petrology, and geochemistry". Geochimica et Cosmochimica Acta. 41 (6): 711–740. Bibcode:1977GeCoA..41..711B. doi:10.1016/0016-7037(77)90044-8.
  2. ^ Hsu, W. (2003). "Minor element zoning and trace element geochemistry of pallasites". Meteoritics & Planetary Science. 38 (8): 1217–1241. Bibcode:2003M&PS...38.1217H. doi:10.1111/j.1945-5100.2003.tb00309.x. S2CID 73597247.
  3. ^ O. Richard Norton. The Cambridge encyclopedia of meteorites. Cambridge, Cambridge University Press, 2002. ISBN 0-521-62143-7.
  4. ^ M. K. Weisberg; T. J. McCoy, A. N. Krot (2006). "Systematics and Evaluation of Meteorite Classification". In D. S. Lauretta; H. Y. McSween, Jr. (eds.). Meteorites and the early solar system II (PDF). Tucson: University of Arizona Press. pp. 19–52. ISBN 978-0816525621. Retrieved 15 December 2012.
  5. ^ Edward R.D. Scott, "Impact Origins for Pallasites," Lunar and Planetary Science XXXVIII, 2007.
  6. ^ Windmill, Richard J. (March 2022). "Isotopic evidence for pallasite formation by impact mixing of olivine and metal during the first 10 million years of the Solar System". PNAS Nexus. 1 (1): pgac015. doi:10.1093/pnasnexus/pgac015. PMC 9802258. PMID 36712802.
  7. ^ Chladni (1798). "Observation on a mass of iron found in Siberia by Professor Pallas, and other masses of the like kind, with some conjectures respecting their connection with certain natural phenomena". The Philosophical Magazine. 2 (5): 1–8. doi:10.1080/14786449808676869.
  8. ^ Chladni, Ernst Florens Friedrich (1794). Über den Ursprung der von Pallas gefundenen und anderer ihr ähnlicher Eisenmassen und über einige damit in Verbindung stehende Naturerscheinungen [On the origin of the iron masses found by Pallas and others similar to it, and on some natural phenomena associated with them] (in German). Riga, Latvia: Johann Friedrich Hartknoch. ISBN 9783111274386.
  9. ^ Meteoritical Bulletin Database
  10. ^ MetBase
  11. ^ "Meteorites Japan". Archived from the original on 2008-05-06. Retrieved 2009-04-13.
  12. ^ Mammoth meteorite unearthed, January 2006 about the October 2005 find
  13. ^ CNN: Unusual meteorite found in Kansas, October 16, 2006.
  14. ^ "Haviland, Kansas: Kansas Meteorite Museum". RoadsideAmerica.com. Retrieved April 20, 2022.
  15. ^ The original location of the Krasnojarsk meteorite was: 54° 54' N, 91° 48' E. See:

See also