Promethium(III) bromide
Names
IUPAC name
Promethium(III) bromide
Identifiers
3D model (JSmol)
  • [Pm+3].[Br-].[Br-].[Br-]
Properties
PmBr3
Molar mass 385
Related compounds
Other anions
Promethium(III) fluoride
Promethium(III) chloride
Promethium(III) iodide
Other cations
Neodymium(III) bromide
Samarium(III) bromide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Promethium(III) bromide is an inorganic compound, with the chemical formula of PmBr3. It is radioactive.

Preparation

Promethium(III) bromide can be obtained by reacting hydrogen bromide and promethium(III) oxide:[1]

Pm2O3 + 6 HBr —500℃→ 2 PmBr3 + 3 H2O

Promethium(III) bromide hydrate cannot be heated to form its anhydrous form. Instead it decomposes in water to form promethium oxybromide:[2]

PmBr3 + H2O(g) → PmOBr + 2 HBr

References

  1. ^ W. R. Wilmarth, G. M. Begun, R. G. Haire, et al. Raman spectra of Pm2O3, PmF3, PmCl3, PmBr3 and PmI3. Journal of Raman Spectroscopy, 2005. 19(4)
  2. ^ V Wishnevsky, W Theissig, F Weigel. The vapor phase hydrolysis of lanthanide(III) bromides IV: Heat and free energy of the reaction PmBr3 + H2O = PmOBr + 2 HBr. Journal of the Less Common Metals. 1984, 99(2): 321-329. doi:10.1016/0022-5088(84)90230-3