Formaldehyde
Skeletal fomula o formaldehyde wi explicit hydrogens addit
Skeletal fomula o formaldehyde wi explicit hydrogens addit
Spacefill model o formaldehyde
Spacefill model o formaldehyde
Baw an stick model o formaldehyde
Names
Preferred IUPAC name
Formaldehyde[1]
Seestematic IUPAC name
Methanal[1]
Ither names
Methyl aldehyde
Methylene glycol
Methylene oxide
Formalin (aqueous solution)
Formol
Carbonyl hydride
Identifiers
CAS Nummer
3D model (JSmol)
3DMet B00018
Beilstein Reference
1209228
ChEBI
ChEMBL
ChemSpider
DrugBank
EC Nummer 200-001-8
Gmelin Reference 445
IUPHAR/BPS
KEGG
MeSH Formaldehyde
RTECS nummer LP8925000
UNII
UN nummer 2209
Properties[6]
CH2O
Molar mass 30.03 g·mol−1
Appearance Colorless gas
Density 0.8153 g/cm3 (−20 °C)[2]
Meltin pynt −92 °C (−134 °F; 181 K)
Bylin pynt −19 °C (−2 °F; 254 K)[2]
Solubility in watter
400 g dm−3
log P 0.350
Vapour pressur < 1 atm[3]
Acidity (pKa) 13.27 [4][5]
Magnetic susceptibility -18.6·10−6 cm3/mol
Dipole moment
2.33 D
Structur
Pynt group C2v
Molecular shape Trigonal planar
Pharmacology
ATCvet code
QP53AX19 (WHO)
Hazards
Safety data sheet MSDS
EU clessification Toxic (T)
Corrosive (C)
Carc. Cat. 1
R-phrases R23/24/25 R34 R43 R45
S-phrases (S1/2) S26 S36/37/39 S45 S51 S53 S60
NFPA 704
NFPA 704 four-colored diamondFlammability code 4: Will rapidly or completely vaporize at normal atmospheric pressur an temperatur, or is readily dispersed in air an will burn readily. Flash pynt ablo 23 °C (73 °F). E.g., propaneHealth code 3: Short exposur could cause serious temporary or residual injury. E.g., chlorine gasReactivity code 0: Normally stable, even unner fire exposur condeetions, an is nae reactive wi watter. E.g., liquid nitrogenSpecial hazard COR: Corrosive; strang acid or base. E.g., sulfuric acid, potassium hydroxide
4
3
0
COR
Flash pynt 64 °C (147 °F; 337 K)
Autoigneetion
temperatur
430 °C (806 °F; 703 K)
Explosive leemits 7–73%
Lethal dose or concentration (LD, LC):
LD50 (Median dose)
100 mg/kg (oral, rat)[9]
LC50 (Median concentration)
333 ppm (moose, 2 hr)
815 ppm (rat, 30 min)[10]
LCLo (Lawest published)
333 ppm (cat, 2 hr)[10]
US heal exposur leemits (NIOSH):
PEL (Permissible)
TWA 0.75 ppm ST 2 ppm (as formaldehyde an formalin)[7][8]
REL (Recommendit)
Ca TWA 0.016 ppm C 0.1 ppm [15-minute][7]
IDLH (Immediate danger)
Ca [20 ppm][7]
Relatit compoonds
Relatit aldehydes
Acetaldehyde

Butyraldehyde
Decanal
Heptanal
Hexanal
Nonanal
Octadecanal
Octanal
Pentanal
Propionaldehyde

Relatit compoonds
methanol
formic acid
Except whaur itherwise notit, data are gien for materials in thair staundart state (at 25 °C [77 °F], 100 kPa).
YesY verify (whit is YesYN ?)
Infobox references

Formaldehyde is a naiturally occurring organic compoond wi the formula CH2O (H-CHO). It is the simplest o the aldehydes (R-CHO) an is an aa kent bi its seestematic name methanal. The common name o this substance comes frae its seemilarity an relation tae formic acid.

References

  1. a b Nomenclature of Organic Chemistry : IUPAC Recommendations and Preferred Names 2013 (Blue Book). Cambridge: The Royal Society of Chemistry. 2014. p. 908. doi:10.1039/9781849733069-FP001. ISBN 978-0-85404-182-4.
  2. a b Formaldehyde (PDF), SIDS Initial Assessment Report, International Programme on Chemical Safety
  3. Spence, Robert, and William Wild. "114. The vapour-pressure curve of formaldehyde, and some related data." Journal of the Chemical Society (Resumed) (1935): 506-509
  4. https://pubchem.ncbi.nlm.nih.gov/compound/formaldehyde#section=Odor-Threshold
  5. http://chemistry.stackexchange.com/questions/12232/acidity-of-aldehydes
  6. Weast, Robert C., ed. (1981). CRC Handbook of Chemistry and Physics (62nd ed.). Boca Raton, FL: CRC Press. pp. C–301, E–61. ISBN 0-8493-0462-8.
  7. a b c NIOSH Pocket Guide tae Chemical Hazards 0293
  8. NIOSH Pocket Guide tae Chemical Hazards 0294
  9. http://chem.sis.nlm.nih.gov/chemidplus/rn/50-00-0
  10. a b "Formaldehyde". Immediately Dangerous to Life and Health. National Institute for Occupational Safety and Health (NIOSH).