The World Group II was the second highest level of Fed Cup competition in 2016. The winning nations advanced to the World Group play-offs, and the losing nations were relegated to the World Group II play-offs.

Slovakia vs. Australia

Slovakia 2	Aegon Arena, Bratislava, Slovakia[1] 6–7 February 2016 Hard (indoors)		Australia 3
1 2 3 1 Anna Karolína Schmiedlová Arina Rodionova 5 7 7 5 6 0   2 Jana Čepelová Samantha Stosur 3 6 4 6     3 Anna Karolína Schmiedlová Samantha Stosur 65 77 5 7     4 Dominika Cibulková Kimberly Birrell 6 3 6 1     5 Jana Čepelová / Daniela Hantuchová Casey Dellacqua / Samantha Stosur 7 5 1 6 2 6

Serbia vs. Spain

Serbia 0	Kraljevo Sports Centre, Kraljevo, Serbia[2] 6–7 February 2016 Hard (indoors)		Spain 4
1 2 3 1 Ivana Jorović Garbiñe Muguruza 3 6 1 6     2 Jelena Janković Carla Suárez Navarro 4 6 2 6     3 Jelena Janković Garbiñe Muguruza 3 6 4 6     4 Bojana Jovanovski Carla Suárez Navarro       not played 5 Ivana Jorović / Nina Stojanović Lara Arruabarrena / Lourdes Domínguez Lino 6 4 66 78 [7] [10]

United States vs. Poland

United States 4	Holua Tennis Center, Kailua Kona, United States[3] 6–7 February 2016 Hard (outdoors)		Poland 0
1 2 3 1 Sloane Stephens Magda Linette 6 2 6 4     2 Venus Williams Paula Kania 7 5 6 2     3 Venus Williams Magda Linette 6 1 6 2     4 Sloane Stephens Paula Kania       not played 5 Bethanie Mattek-Sands / Coco Vandeweghe Klaudia Jans-Ignacik / Paula Kania 6 1 7 5

Canada vs. Belarus

Canada 2	Pavillon de l'éducation physique et des sports de l'Université Laval, Québec City, Canada[4] 6–7 February 2016 Hard (indoors)		Belarus 3
1 2 3 1 Françoise Abanda Aliaksandra Sasnovich 4 6 6 2 3 6   2 Aleksandra Wozniak Olga Govortsova 6 2 6 2     3 Françoise Abanda Olga Govortsova 6 4 6 4     4 Aleksandra Wozniak Aliaksandra Sasnovich 4 6 4 6     5 Gabriela Dabrowski / Carol Zhao Olga Govortsova / Aliaksandra Sasnovich 2 6 4 6