Arsenide iodides or iodide arsenides are compounds containing anions composed of iodide (I−) and arsenide (As3−). They can be considered as mixed anion compounds. They are in the category of pnictidehalides. Related compounds include the arsenide chlorides, arsenide bromides, phosphide iodides, and antimonide iodides.

List

formula system space group unit cell Å volume density comment ref
Ca2AsI trigonal R3m a=4.397, c = 22.29, Z = 3 3.76 brown [1][2]
Ca3AsI3 cubic I4132 a=12.42 3.99 colourless [1]
Cu2P1.8As1.2I2 monoclinic P21/c a = 15.477, b = 13.200, c = 15.421, β = 115.406°, Z = 16 Cu exchangeable with Ag; band gap 1.2 eV [3]
Ge38As8I8 cubic P43m a=10.611 metallic; water and air stable [4]
Ag2P1.8As1.2I2 monoclinic P21/c a = 15.84, b = 13.68, c = 15.58 and β = 117.63° Z=16 [5]
Sn24As19.3I8 cubic a=22.179 Z=8 black [6]
Sn20.5□3.5As22I8 cubic a=22.1837 low thermal conductivity [7]
Sn24AsxP19.3−xI8 x=0-16 cubic Pm3n a = 10.9358—11.1495 [8]
Sn19.3Cu4.7As22I8 cubic Pm3n a = 11.1736 Z = 1 1394.4 6.236 clathrate; Zintl; diamagnetic [9]
Sn24–x–δInxAs22–yI8 cubic Pm3n a = 11.088 (x = 0) to a = 11.343 (x = 10.7) clathrate [10]
La2AsI2 trigonal P3m1 a=4.3795 c=10.910 5.56 [11]
Hg4AsI5 orthorhombic Cmca a=11.927 b=12.128 c=19.776 Z=8 2859.0 7.025 red [12]
Hg4As2I3 cubic Pa3 a=12.999 Z=8 2196 8.06 black [13]
HgI2⋅As4S4 monoclinic P21/c a=9.433 b=14.986 c=11.624 β=127.72° Z=4 1299 4.509 orange; dec 212 °C [14]
Hg5AsS2I3 monoclinic C2/c a=13.339 b=8.444 c=13.428 β=118.352 Z=4 1331.2 7.599 black; dec 150 °C [15]
Hg3AsSe4I hexagonal P63mc a = 7.6902, c = 9.968 Z=2 red; air stable [16]
[Hg7As4](AgI3)2 cubic Pa a = 13.138 Z = 4 [17][18]
(Hg2As)2(CdI4) monoclinic P21 a=7.945, b=12.934, c=8.094, β=116.898° 741.7 [19]
[Hg7As4I3](SnI3) cubic P213 a = 13.110, Z = 4 2253.2 7.617 black [20]

References

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  2. ^ Hadenfeldt, C.; Herdejürgen, H. (February 1987). "Darstellung und Kristallstruktur der Calciumnitridhalogenide Ca2NCl und Ca2NBr". Zeitschrift für anorganische und allgemeine Chemie (in German). 545 (2): 177–183. doi:10.1002/zaac.19875450220. ISSN 0044-2313.
  3. ^ Jayasekera, Buddhimathie; Aitken, Jennifer A.; Heeg, Mary Jane; Brock, Stephanie L. (2003-02-01). "Toward an Arsenic Analogue of Hittorf's Phosphorus: Mixed Pnicogen Chains in Cu 2 P 1.8 As 1.2 I 2". Inorganic Chemistry. 42 (3): 658–660. doi:10.1021/ic0258936. ISSN 0020-1669. PMID 12562174.
  4. ^ von Schnering, Hans-Georg; Menke, Heinz (January 1972). "Ge38P8I8 and Ge38As8I8, a New Class of Compounds with Clathrate Structure". Angewandte Chemie International Edition in English. 11 (1): 43–44. doi:10.1002/anie.197200431. ISSN 0570-0833.
  5. ^ Jayasekera, Buddhimathie; Brock, Stephanie L. (2002). "Ag Ion-Exchange Reactions of Cu 2 P 3 I 2 and Cu 2 P 1.8 As 1.2 I 2". MRS Proceedings. 755: DD6.12. doi:10.1557/PROC-755-DD6.12. ISSN 0272-9172.
  6. ^ Shatruk, Mikhail M.; Kovnir, Kirill A.; Shevelkov, Andrei V.; Presniakov, Igor A.; Popovkin, Boris A. (1999-07-01). "First Tin Pnictide Halides Sn 24 P 19.3 I 8 and Sn 24 As 19.3 I 8 : Synthesis and the Clathrate-I Type of the Crystal Structure". Inorganic Chemistry. 38 (15): 3455–3457. doi:10.1021/ic990153r. ISSN 0020-1669. PMID 11671088.
  7. ^ Zaikina, Julia V.; Kovnir, Kirill A.; Sobolev, Alexei V.; Presniakov, Igor A.; Prots, Yuri; Baitinger, Michael; Schnelle, Walter; Olenev, Andrei V.; Lebedev, Oleg I.; Van Tendeloo, Gustaaf; Grin, Yuri (2007-06-15). "Sn20.5□3.5As22I8: A Largely Disordered Cationic Clathrate with a New Type of Superstructure and Abnormally Low Thermal Conductivity". Chemistry - A European Journal. 13 (18): 5090–5099. doi:10.1002/chem.200601772. PMID 17385200.
  8. ^ Kelm, E. A.; Zaikina, Yu. V.; Dikarev, E. V.; Shevelkov, A. V. (April 2009). "Distribution of phosphorus and arsenic atoms in the solid solution Sn24As x P19.3-x I8 with the structure of clathrate-I". Russian Chemical Bulletin. 58 (4): 746–750. doi:10.1007/s11172-009-0089-0. ISSN 1066-5285. S2CID 93897495.
  9. ^ Kovnir, Kirill A.; Sobolev, Alexei V.; Presniakov, Igor A.; Lebedev, Oleg I.; Van Tendeloo, Gustaaf; Schnelle, Walter; Grin, Yuri; Shevelkov, Andrei V. (2005-11-01). "Sn 19.3 Cu 4.7 As 22 I 8 : a New Clathrate-I Compound with Transition-Metal Atoms in the Cationic Framework" (PDF). Inorganic Chemistry. 44 (24): 8786–8793. doi:10.1021/ic051160k. ISSN 0020-1669. PMID 16296833.
  10. ^ Kelm, Evgeny A.; Olenev, Andrei V.; Bykov, Mikhail A.; Sobolev, Alexey V.; Presniakov, Igor A.; Kulbachinskii, Vladimir A.; Kytin, Vladimir G.; Shevelkov, Andrei V. (November 2011). "Synthesis, Crystal Structure, and Thermoelectric Properties of Clathrates in the Sn-In-As-I System". Zeitschrift für anorganische und allgemeine Chemie. 637 (13): 2059–2067. doi:10.1002/zaac.201100287.
  11. ^ Oeckler, Oliver; Mattausch, Hansjürgen; Simon, Arndt (2007-11-01). "Einige Phosphidhalogenide des Lanthans und verwandte Verbindungen/ Some Phosphide Halides of Lanthanum and Related Compounds". Zeitschrift für Naturforschung B. 62 (11): 1377–1382. doi:10.1515/znb-2007-1105. ISSN 1865-7117. S2CID 95077294.
  12. ^ Oleneva, O. S.; Shestimerova, T. A.; Olenev, A. V.; Dikarev, E. V.; Shevelkov, A. V. (May 2006). "Synthesis and the crystal and electronic structure of Hg4AsI5". Russian Chemical Bulletin. 55 (5): 762–765. doi:10.1007/s11172-006-0329-5. ISSN 1066-5285. S2CID 97240594.
  13. ^ Labbé, Ph.; Ledésert, M.; Raveau, B.; Rebbah, A. (1989-08-01). "Crystal structure of Hg 4 As 2 I 3". Zeitschrift für Kristallographie - Crystalline Materials. 187 (1–4): 117–124. doi:10.1524/zkri.1989.187.14.117. ISSN 2196-7105. S2CID 101349696.
  14. ^ Bräu, Michael F.; Pfitzner, Arno (2006-07-03). "HgI2⋅As4S4: An Adduct from HgI2 Molecules and Undistorted As4S4 Cages". Angewandte Chemie International Edition. 45 (27): 4464–4467. doi:10.1002/anie.200600690. ISSN 1433-7851. PMID 16758498.
  15. ^ Liu, Yong; Zeng, Hui-Yi; Liu, Bin-Wen; Wang, Geng-E; Guo, Guo-Cong (May 2015). "Hg 5 AsS 2 I 3 – A Narrow-Band-Gap 2D Layered Compound with Different Trapped I – Anions". European Journal of Inorganic Chemistry. 2015 (14): 2402–2406. doi:10.1002/ejic.201500150. ISSN 1434-1948.
  16. ^ Beck, Johannes; Hedderich, Sylvia; Köllisch, Klaus (2000-12-01). "Hg 3 AsE 4 X (E = S, Se; X = Cl, Br, I), a Family of Isotypic Compounds with an Acentric, Layered Structure". Inorganic Chemistry. 39 (25): 5847–5850. doi:10.1021/ic0003527. ISSN 0020-1669. PMID 11151388.
  17. ^ Olenev, Andrei V.; Baranov, Alexei I.; Oleneva, Olga S.; Vorontsov, Ivan I.; Antipin, Mikhail Yu.; Shevelkov, Andrei V. (March 2003). "Synthesis, Crystal and Electronic Structure of [Hg 7 As 4 ](AgI 3 ) 2 , a Novel Supramolecular Complex with the Off-Plane AgI 3 2− Guest Anion". European Journal of Inorganic Chemistry. 2003 (6): 1053–1057. doi:10.1002/ejic.200390137. ISSN 1434-1948.
  18. ^ Borisov, S. V.; Pervukhina, N. V.; Magarill, S. A. (February 2020). "Crystallographic Analysis and Symmetry Generation for Some Structures with [As2] and [Hgn] (n = 2, 3) Cluster Groups". Journal of Structural Chemistry. 61 (2): 259–266. doi:10.1134/S0022476620020109. ISSN 0022-4766. S2CID 220540955.
  19. ^ Zou, Jian-Ping; Wu, Dong-Sheng; Huang, Shu-Ping; Zhu, Jing; Guo, Guo-Cong; Huang, Jin-Shun (March 2007). "Synthesis, crystal and band structures, and properties of a new supramolecular complex (Hg2As)2(CdI4)". Journal of Solid State Chemistry. 180 (3): 805–811. Bibcode:2007JSSCh.180..805Z. doi:10.1016/j.jssc.2006.11.018.
  20. ^ Olenev, Andrei V.; Baranov, Alexei I.; Shevelkov, Andrei V.; Popovkin, Boris A. (2000). "[Hg7As4I3](SnI3): Trapping the SnI31– Anion in the Cavities of the Unprecedented Mercury-Arsenic-Iodine Network". European Journal of Inorganic Chemistry. 2000 (2): 265–270. doi:10.1002/(SICI)1099-0682(200002)2000:2<265::AID-EJIC265>3.0.CO;2-A.
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