Bismuth telluride (Bi2Te3) is a gray powder that is a compound of bismuth and tellurium also known as bismuth(III) telluride. It is a semiconductor, which, when alloyed with antimony or selenium, is an efficient thermoelectric material for refrigeration or portable power generation. Bi2Te3 is a topological insulator, and thus exhibits thickness-dependent physical properties.
Properties as a thermoelectric material
Bismuth telluride is a narrow-gap layered semiconductor with a trigonal unit cell. The valence and conduction band structure can be described as a many-ellipsoidal model with 6 constant-energy ellipsoids that are centered on the reflection planes.[4]Bi2Te3 cleaves easily along the trigonal axis due to Van der Waals bonding between neighboring tellurium atoms. Due to this, bismuth-telluride-based materials used for power generation or cooling applications must be polycrystalline. Furthermore, the Seebeck coefficient of bulk Bi2Te3 becomes compensated around room temperature, forcing the materials used in power-generation devices to be an alloy of bismuth, antimony, tellurium, and selenium.[5]
Recently, researchers have attempted to improve the efficiency of Bi2Te3-based materials by creating structures where one or more dimensions are reduced, such as nanowires or thin films. In one such instance n-type bismuth telluride was shown to have an improved Seebeck coefficient (voltage per unit temperature difference) of −287 μV/K at 54 °C,[6] However, one must realize that Seebeck coefficient and electrical conductivity have a tradeoff: a higher Seebeck coefficient results in decreased carrier concentration and decreased electrical conductivity.[7]
Bismuth telluride is a well-studied topological insulator. Its physical properties have been shown to change at highly reduced thicknesses, when its conducting surface states are exposed and isolated. These thin samples are obtained through either epitaxy or mechanical exfoliation.
Epitaxial growth methods such as molecular beam epitaxy and metal organic chemical vapor deposition are common methods of obtaining thin Bi2Te3 samples. The stoichiometry of samples obtained through such techniques can vary greatly between experiments, so Raman spectroscopy is often used to determine relative purity. However, thin Bi2Te3 samples are resistant to Raman spectroscopy due to their low melting point and poor heat dispersion.[9]
The crystalline structure of Bi2Te3 allows for mechanical exfoliation of thin samples by cleaving along the trigonal axis. This process is significantly lower in yield than epitaxial growth, but produces samples without defects or impurities. Similar to extracting graphene from bulk graphite samples, this is done by applying and removing adhesive tape from successively thinner samples. This procedure has been used to obtain Bi2Te3 flakes with a thickness of 1 nm.[10] However, this process can leave significant amounts of adhesive residue on a standard Si/SiO2substrate, which in turn obscure atomic force microscopy measurements and inhibit the placement of contacts on the substrate for purposes of testing. Common cleaning techniques such as oxygen plasma, boiling acetone and isopropyl alcohol are ineffective in removing residue.[11]
Occurrence and preparation
The mineral form of Bi2Te3 is tellurobismuthite which is moderately rare.[12][13] There are many natural bismuth tellurides of different stoichiometry, as well as compounds of the Bi-Te-S-(Se) system, like Bi2Te2S (tetradymite). These bismuth tellurides are part of the tetradymite group of minerals.[14]
Bismuth telluride may be prepared simply by sealing mixed powders of bismuth and tellurium metal in a quartz tube under vacuum (critical, as an unsealed or leaking sample may explode in a furnace) and heating it to 800 °C in a muffle furnace.
^Feutelais, Y.; Legendre, B.; Rodier, N.; Agafonov, V. (1993). "A study of the phases in the bismuth – tellurium system". Materials Research Bulletin. 28 (6): 591. doi:10.1016/0025-5408(93)90055-I.
^Caywood, L. P.; Miller, G. (1970). "Anisotropy of the constant energy surfaces in p-type Bi2Te3 and Bi2Se3 from galvanomagnetic coefficients". Phys. Rev. B. 2 (8): 3209. Bibcode:1970PhRvB...2.3209C. doi:10.1103/PhysRevB.2.3209.
^Tan, J. (2005). "Thermoelectric properties of bismuth telluride thin films deposited by radio frequency magnetron sputtering". In Cane, Carles; Chiao, Jung-Chih; Vidal Verdu, Fernando (eds.). Smart Sensors, Actuators, and MEMS II. Vol. 5836. pp. 711–718. Bibcode:2005SPIE.5836..711T. doi:10.1117/12.609819. S2CID123199126.
^Teweldebrhan, D.; Goyal, V.; Balandin, A. A (2010). "From Graphene to Bismuth Telluride: Mechanical Exfoliation of Quasi-2D Crystals for Applications in Thermoelectrics and Topological Insulators". Nano Letters. 10 (12): 1209–18. Bibcode:2010NanoL..10.1209T. doi:10.1021/nl903590b. PMID20205455.
^Teweldebrhan, Desalegne; Balandin, Alexander A. (2010). ""Graphene-Like" Exfoliation of Atomically-Thin Films of Bi". ECS Transactions: 103–117. doi:10.1149/1.3485611. S2CID139017503.
