Borate nitrates are mixed anion compounds containing separate borate and nitrate anions. They are distinct from the boronitrates where the borate is linked to a nitrate via a common oxygen atom.

List

chem mw crystal system space group unit cell Å volume density comment references
Na3(NO3)[B6O10] [1]
K3B6O10NO3 [2]
K3Na[B6O9(OH)3]NO3 Pnnm a=13.208, b=9.107, c=12.325 Z=4 [3]
Co3B7O13NO3 [4]
[Co(H2O)6](NO3)2·[Co{B3O3(OH)4}2(H2O)4]·2H2O [5]
[Ni(H2O)6](NO3)2·[Ni{B3O3(OH)4}2(H2O)4]·2H2O [5]
Ni3B7O13NO3 [4]
K7Ni[B18O24(OH)9](NO3)6· (H3BO3) 1497.96 trigonal R3 a=12.2229 c=54.784 Z=6 7088 2.11 green [6]
Cu3B7O13NO3 [4]
Zn3B7O13NO3 [4]
[Zn(H2O)6](NO3)2·[Zn{B3O3(OH)4}2(H2O)4]·2H2O monoclinic P21/c a = 11.282, b = 6.5374, c = 17.668, β = 100.981° [5]
Rb3(NO3)[B6O10] [2]
Cd3B7O13NO3 [4]
La[B5O8(OH)]NO3
La[B5O8(OH)]NO3·2H2O monoclinic P21/n a=6.540, b=15.550, c=10.672, β=90.44° and Z=4 [7]
cerium(III) aquahydroxidooctaoxidopentaborate nitrate dihydrate Ce[B5O8(OH)(H2O)]NO3·2H2O 455.24 monoclinic P21/n a=6.444 b=15.572 c=10.745 β=90.395 Z=4 1078.2 2.904 colourless [8]
Pr[B5O8(OH)(H2O)x]NO3·2H2O monoclinic P21/n a=6.419, b=15.518, c=10.684, with β=90.54° Z=4 1064.3 [9]
Pr7(BO3)3(NO3)N3O hexagonal P63 a=10.6834 c=6.6752 Z=2 6.457 green; contains N(OBO3)3 clusters, oxide and nitride [10]
Nd7(BO3)3(NO3)N3O hexagonal P63 a=10.6446 c=6.6339 Z=2 6.664 purplish-blue;contains N(OBO3)3 clusters oxide, and nitride;SHG [10]
Nd[B5O8(OH)(H2O)x]NO3·2H2O P21/n a = 6.4285, b = 15.5258, c = 10.7052, β = 90.39° 1068.44 [11]
Sm[B5O8(OH)(H2O)x]NO3·2H2O P21/n a = 6.4409, b = 15.4199, c = 10.5097, β = 90.33° 1043.79 [11]
Lu2B2O5(NO3)2·2H2O triclinic P1 a=7.8952, b=9.8862, c=14.6033, α=90.83, β=101.75, γ=110.02° Z=4 [6][12]
Pb2(BO3)(NO3) 535.20 hexagonal P63mc a=5.0731 c=13.040 Z=2 290.64 6.116 colourless SHG 9×KDP [13]
[Pb3(B3O7)](NO3) 828.01 Pnma a=10.3481 b=7.8908 c=11.2123 Z=4 914.54 6.007 colourless [14]

References

  1. ^ Ortner, Teresa S.; Schildhammer, Daniel; Tribus, Martina; Joachim, Bastian; Huppertz, Hubert (2017-03-01). "Synthesis and characterization of the alkali borate-nitrates Na3–x Kx[B6O10]NO3 (x=0.5, 0.6, 0.7)". Zeitschrift für Naturforschung B. 72 (3): 215–223. doi:10.1515/znb-2016-0242. ISSN 1865-7117. S2CID 99165997.
  2. ^ a b Zhang, Qiqi; Zhang, Fangfang; Li, Fuming; Han, Shujuan; Yang, Zhihua; Pan, Shilie (2021-02-13). "M3B6O10NO3 (M = K, Rb): Two new alkali metal borate‐nitrates with noncentrosymmetric structures". European Journal of Inorganic Chemistry. 2021 (13): 1297–1304. doi:10.1002/ejic.202001167. ISSN 1434-1948. S2CID 233784768.
  3. ^ Ortner, Teresa S.; Wurst, Klaus; Perfler, Lukas; Tribus, Martina; Huppertz, Hubert (January 2015). "Hydrothermal synthesis and characterization of the first mixed alkali borate-nitrate K3Na[B6O9(OH)3]NO3". Journal of Solid State Chemistry. 221: 66–72. Bibcode:2015JSSCh.221...66O. doi:10.1016/j.jssc.2014.09.016.
  4. ^ a b c d e Bither, Tom A.; Young, Howard S. (1974-08-01). "Nitrato- and fluoroboracites M3B7O13NO3 and M3B7O13F". Journal of Solid State Chemistry. 10 (4): 302–311. Bibcode:1974JSSCh..10..302B. doi:10.1016/0022-4596(74)90039-5. ISSN 0022-4596.
  5. ^ a b c Liu, Ying; Deng, Jun-Xia; Pan, Chun-Yang (2020-05-04). "Synthesis and Structural Manipulation of a Polyanionic Zincoborate [Zn(H2O)6](NO3)2·[Zn{B3O3(OH)4}2(H2O)4]·2H2O by the Molten Salt Method and its Potential Application as a Flame Retardant". Journal of Cluster Science. 32 (2): 469–477. doi:10.1007/s10876-020-01806-7. ISSN 1040-7278. S2CID 218495402.
  6. ^ a b Zoller, Michael; Wurst, Klaus; Huppertz, Hubert (2019-10-25). "Synthesis of the first nickel borate nitrate K7Ni[B18O24(OH)9](NO3)6· (H3BO3)". Zeitschrift für Naturforschung B. 74 (10): 757–764. doi:10.1515/znb-2019-0126. ISSN 1865-7117. S2CID 202872565.Open access icon CC-BY can use images
  7. ^ Zhao, Biao-Chun; Sun, Wei; Ren, Wei-Jian; Huang, Ya-Xi; Li, Zucheng; Pan, Yuanming; Mi, Jin-Xiao (October 2013). "Hygroscopic La[B5O8(OH)]NO3·2H2O: Insight into the evolution of borate fundamental building blocks". Journal of Solid State Chemistry. 206: 91–98. Bibcode:2013JSSCh.206...91Z. doi:10.1016/j.jssc.2013.07.032.
  8. ^ Sun, Wei; Zhu, Teng-Teng; Zhao, Biao-Chun; Huang, Ya-Xi; Mi, Jin-Xiao (2012-05-15). "Redetermination of Ce[B 5 O 8 (OH)(H 2 O)]NO 3 ·2H 2 O". Acta Crystallographica Section E. 68 (5): i33–i34. doi:10.1107/S1600536812016169. ISSN 1600-5368. PMC 3344287. PMID 22590053.
  9. ^ Ortner, Teresa S.; Huppertz, Hubert (2017-09-26). "Hydrothermal synthesis and characterization of the praseodymium borate-nitrate Pr[B5O8(OH)(H2O)0.87]NO3·2H2O". Zeitschrift für Naturforschung B. 72 (9): 677–685. doi:10.1515/znb-2017-0121. ISSN 1865-7117. S2CID 103777780.
  10. ^ a b Katrych, Sergiy; Arakcheeva, Alla; Sienkiewicz, Andrzej; Forró, László; Ivšić, Trpimir (2020-12-15). "High-Pressure Synthesis of Rare-Earth Borate-Nitrate Crystals for Second Harmonic Generation". Inorganic Chemistry. 60 (1): 286–291. doi:10.1021/acs.inorgchem.0c02909. ISSN 0020-1669. PMID 33320648. S2CID 229283287.
  11. ^ a b Ortner, Teresa S.; Wurst, Klaus; Joachim, Bastian; Huppertz, Hubert (August 2016). "Syntheses, Structure Elucidation, and Characterization of the Borate-Nitrates RE[B 5 O 8 (OH)(H 2 O) x ]NO 3 ·2H 2 O [RE = Nd ( x = 0.85), Sm ( x = 0)]: Syntheses, Structure Elucidation, and Characterization of the Borate-Nitrates RE[B 5 O 8 (OH)(H 2 O) x ]NO 3 ·2H 2 O [RE = Nd ( x = 0.85), Sm ( x = 0)]". European Journal of Inorganic Chemistry. 2016 (22): 3659–3665. doi:10.1002/ejic.201600480.
  12. ^ Ortner, Teresa S.; Wurst, Klaus; Hejny, Clivia; Huppertz, Hubert (January 2016). "Hydrothermal synthesis and characterization of the lutetium borate–nitrate Lu2B2O5(NO3)2·2H2O". Journal of Solid State Chemistry. 233: 329–334. Bibcode:2016JSSCh.233..329O. doi:10.1016/j.jssc.2015.11.005.
  13. ^ Song, Jun-Ling; Hu, Chun-Li; Xu, Xiang; Kong, Fang; Mao, Jiang-Gao (2015-03-16). "A Facile Synthetic Route to a New SHG Material with Two Types of Parallel π-Conjugated Planar Triangular Units". Angewandte Chemie. 127 (12): 3750–3753. Bibcode:2015AngCh.127.3750S. doi:10.1002/ange.201412344.
  14. ^ Song, Jun-Ling; Hu, Chun-Li; Xu, Xiang; Kong, Fang; Mao, Jiang-Gao (2013-08-05). "Pb 2 B 3 O 5.5 (OH) 2 and [Pb 3 (B 3 O 7 )](NO 3 ): Facile Syntheses of New Lead(II) Borates by Simply Changing the pH Values of the Reaction Systems". Inorganic Chemistry. 52 (15): 8979–8986. doi:10.1021/ic401175r. ISSN 0020-1669. PMID 23834222.
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