Borate sulfides are chemical mixed anion compounds that contain any kind of borate and sulfide ions. They are distinct from thioborates in which sulfur atoms replace oxygen in borates. There are also analogous borate selenides, with selenium ions instead of sulfur.

List

name chem mw crystal system space group unit cell volume density comments references
Zn4B6O12S I43m NLO 1.9 × KDP [1]
cadmium sulfur boracite Cd3B7O13S2 cubic F43c [2]
La6Nb2MgSB8O26 trigonal P3 a=8.2137 c =8.8601 clear [3]
Ce6Nb2MgSB8O26 trigonal P3 a=8.1672 c=8.8093 clear [3]
Pr6Nb2MgSB8O26 trigonal P3 a=8.1362 c=8.7716 yellowish green [3]
Nd6Nb2MgSB8O26 trigonal P3 a=8.1135 c=8.7469 clear [3]
EBOS Eu2B5O9S 534.03 orthorhombic Pnn2 a=11.2909 b=11.3742 c=6.4440 Z=4 827.57 4.286 black [4]
EBOSI Eu4.5(B5O9)2SI 1238.88 orthorhombic Pnn2 a=11.529 b=11.550 c=6.5070 Z=2 866.5 4.748 yellow-green band gap 1.98 eV [4]
EMSBO Eu9MgS2B20O41 2328.27 Hexagonal P63/m a=8.2708 c=24.919 Z=2 1476.3 5.238 brown [5]
Eu6Ta2MgSB8O26 1832.51 trigonal P3 a=8.0431 c=8.6486 Z=1 484.53 6.280 [6]
Sm3S3BO3 606.04 triclinic P1 a=4.0173 b=7.647 c=11.241  α=91.339  β=91.275 γ=90.349 Z=2 345.14 5.832 green; band gap 2.5 eV [7]
Gd3S3BO3 626.74 triclinic P1 a=3.9725 b=7.5945 c=11.182 α=91.402 β=91.093 γ=90.206 Z=2 337.30 6.173 pale yellow; band gap 2.65 eV [8]

References

  1. ^ Zhou, Wenfeng; Yao, Wen-Dong; Tang, Ru-Ling; Xue, Huaiguo; Guo, Sheng-Ping (2021-06-25). "Second-order nonlinear optical and photoelectric properties of Zn4B6O12S". Journal of Alloys and Compounds. 867: 158879. doi:10.1016/j.jallcom.2021.158879. ISSN 0925-8388. S2CID 233544941.
  2. ^ Gould, R O; Nelmes, R J; Gould, S E B (1981-12-10). "Structural studies of boracites. VII. Cadmium sulphur boracite at room temperature". Journal of Physics C: Solid State Physics. 14 (34): 5259–5267. Bibcode:1981JPhC...14.5259G. doi:10.1088/0022-3719/14/34/008. ISSN 0022-3719.
  3. ^ a b c d Tang, Ru-Ling; Wei, Yu-Long; Chi, Yang; Shi, Zhi-Hui; Liu, Wenlong; Guo, Sheng-Ping (2022-06-13). "Cation Regulation to Investigate the Chalcogenide Borate RE 6 Nb 2 MgSB 8 O 26 (RE = La–Nd) Family". Inorganic Chemistry. 61 (23): 8653–8661. doi:10.1021/acs.inorgchem.2c00033. ISSN 0020-1669. PMID 35622004. S2CID 249095609.
  4. ^ a b Chi, Yang; Xue, Huai-Guo; Guo, Sheng-Ping (2020-01-21). "Designing Sulfide Borate as a Novel Type of Second-Order Nonlinear-Optical Material". Inorganic Chemistry. 59 (2): 1547–1555. doi:10.1021/acs.inorgchem.9b03426. ISSN 0020-1669. PMID 31909601. S2CID 210043683.
  5. ^ Chi, Yang; Xu, Jing; Xue, Huai-Guo; Zhang, Yueping; Chen, Xiaolong; Whangbo, Myung-Hwan; Guo, Sheng-Ping; Deng, Shuiquan (2019-06-19). "Triple-Kagomé-Layer Slabs of Mixed-Valence Rare-Earth Ions Exhibiting Quantum Spin Liquid Behaviors: Synthesis and Characterization of Eu9MgS2B20O41". Journal of the American Chemical Society. 141 (24): 9533–9536. doi:10.1021/jacs.9b04627. ISSN 0002-7863. PMID 31184141. S2CID 184485492.
  6. ^ Shi, Zhi-Hui; Chi, Yang; Yang, Mei; Liu, Wenlong; Guo, Sheng-Ping (2020-03-16). "A Series of Chalcogenide Borates RE6Ta2MgQB8O26 (RE = Sm, Eu, Gd; Q = S, Se) Featuring a B4O10 Cluster". Inorganic Chemistry. 59 (6): 3532–3536. doi:10.1021/acs.inorgchem.0c00086. ISSN 0020-1669. PMID 32090554. S2CID 211263182.
  7. ^ Guo, Sheng-Ping; Chi, Yang; Xue, Huai-Guo (2015-12-07). "Sm 3 S 3 BO 3 : The First Sulfide Borate without S–O and B–S Bonds". Inorganic Chemistry. 54 (23): 11052–11054. doi:10.1021/acs.inorgchem.5b01930. ISSN 0020-1669. PMID 26558599.
  8. ^ Chi, Yang; Guo, Sheng-Ping; Kong, Hong-Jian; Xue, Huai-Guo (2016-08-01). "Crystal and electronic structures, and optical and magnetic properties of novel rare-earth sulfide borates RE3S3BO3 (RE = Sm, Gd)". New Journal of Chemistry. 40 (8): 6720–6727. doi:10.1039/C6NJ00549G. ISSN 1369-9261.
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