Friedrich Wilhelm Strassmann (German:[fʁɪt͡sˈʃtʁasˌman]ⓘ; 22 February 1902 – 22 April 1980) was a German chemist who, with Otto Hahn in December 1938, identified the element barium as a product of the bombardment of uranium with neutrons. Their observation was the key piece of evidence necessary to identify the previously unknown phenomenon of nuclear fission, as was subsequently recognized and published by Lise Meitner and Otto Frisch.[1] In their second publication on nuclear fission in February 1939, Strassmann and Hahn predicted the existence and liberation of additional neutrons during the fission process, opening up the possibility of a nuclear chain reaction.
Personal life and education
Strassmann was born in Boppard, Germany, to Richard Strassmann and Julie Strassmann (née Bernsmann). He was the youngest of nine children. Growing up in Düsseldorf, he developed an interest in chemistry at a young age and conducted chemistry experiments in his parents' home. His family was of modest means, and his father died at a young age, worsening the family's financial situation. Financial considerations limited Strassmann's initial choices of where to pursue his higher education and what subjects they should be.[2][3]
Subsequently, Strassmann received a partial scholarship to the Kaiser Wilhelm Institute for Chemistry in Berlin-Dahlem, beginning in 1929.[4] There he studied radiochemistry with Otto Hahn, who arranged twice for his scholarship to be renewed. When his scholarship expired in September 1932, Strassmann continued to work as a research student in Hahn's laboratory, without a stipend but also without having to pay tuition.[2]
On 20 July 1937 Strassmann married Maria Heckter who was also a chemist. Strassmann was a self-taughtviolinist. He met Maria Heckter Strassmann through a group of young musicians that they both belonged to. The couple had a son, Martin.[2]
Maria Strassmann died of cancer in 1956. In 1959, Strassmann married journalist Irmgard Hartmann. He had known Hartmann for many years, as she was also a member of the same group of young musicians that Strassmann and his wife Maria had belonged to.[2]
Activities during Nazi rule
In 1933 Strassmann resigned from the Society of German Chemists when it became part of a Nazi-controlled public corporation. He was blacklisted by the Nazi regime. As a result, he could not work in the chemical industry nor could he receive his habilitation as required to be an independent researcher in Germany at the time.[2][5]Lise Meitner encouraged Otto Hahn to find an assistantship for Strassmann at half pay, and he eventually became a special assistant to Meitner and Hahn.[2] Strassmann considered himself fortunate, for "despite my affinity for chemistry, I value my personal freedom so highly that to preserve it I would break stones for a living."[5]
Strassman's wife Maria supported his refusal to join the Nazi Party.[2][5] During World War II they concealed a Jewish woman, musician Andrea Wolfenstein, in their apartment for months, putting themselves and their three-year-old son at risk.[6][5][7] Strassmann continued his research in radiochemistry during World War II, although he did not work on weapons development. He disdained the Nazi regime and is reported to have said, "If my work would lead to Hitler having an atomic bomb I would kill myself."[8]
Hahn and Meitner made use of Strassmann's expertise in analytical chemistry in their investigations of the products resulting from bombarding uranium with neutrons. Of these three scientists, only Strassmann was able to remain focused on their joint experimental investigations. Meitner, being Jewish, was forced to leave Nazi Germany, and Hahn had extensive administrative duties.[2]
Nuclear fission experimental setup, reconstructed at the Deutsches Museum, Munich.
In 1937 and 1938, scientists Irène Joliot-Curie and Paul Savič reported results from their investigations on irradiating uranium with neutrons. They were unable to identify the substances that formed as a result of the uranium irradiation. Strassmann, with Hahn, was able to identify the element barium as a major end product in the neutron bombardment of uranium, through a decay chain. The result was surprising because of the large difference in atomic number of the two elements, uranium having atomic number 92 and barium having atomic number 56.[2]
In December 1938, Hahn and Strassmann sent a manuscript to Naturwissenschaften reporting the results of their experiments on detection of barium as a product of neutron bombardment of uranium[9] Otto Frisch confirmed Strassman and Hahn's report experimentally on 13 January 1939.[10] Frisch and Meitner explained Strassman's and Hahn's findings as being from nuclear fission.[1]
In 1944, Hahn received the Nobel Prize for Chemistry for the discovery of nuclear fission, although Fritz Strassmann had been acknowledged as an equal collaborator in the discovery.[11][12]
From 1939 to 1946 working at the Kaiser-Wilhelm Institute, Strassman contributed to research on the fission products of thorium, uranium, and neptunium. In this way, he contributed to the understanding of the radiochemistry of the actinide elements.[2]
Strassmann developed methods for the dating of the age of minerals and other inorganic substances based on the half-life of radioactive elements and the enrichment of decay products. Strassmann and Ernst Walling developed the rubidium-strontium method of radiometric dating in 1936 and 1937, and Strassmann continued this work in 1942 and 1943. His methods are known as emanation methods, and Strassmann's research in this area was fundamental to the field of geochronology.[2]
The Institute consisted of two departments: Mass Spectrometry and Nuclear Physics was Josef Mattauch's department, while Nuclear Chemistry was Strassmann's department. Mattauch was appointed director of the institute. Mattauch developed tuberculosis, and, in his absence, Strassman became acting director in 1948. As of 1949, the Kaiser-Wilhelm Institute was renamed the Max Planck Institute for Chemistry, and moved from Tailfingen to Mainz, Germany.[14]
In 1950 Strassmann became the official director of the institute.[13][14] After Mattauch returned to the institute in 1951, there was considerable conflict over the allocation of resources to their respective departments.[2]
Renewed research
In 1953, Strassmann gave up the directorship, choosing instead to focus on his research and scholarship at the University of Mainz. He succeeded in building up the department's capabilities, and he worked directly with students. Strassmann began these undertakings at the University of Mainz with a few scattered rooms and very little money. He negotiated with the university and with Badische Anilin- und Soda-Fabriken (B.A.S.F.) to fund an institute for the chemical sciences at the university with a focus on nuclear chemistry. He also lobbied the German federal government to fund a neutron generator, a nuclear reactor for research purposes, and a special institute for nuclear chemistry. Strassman's creation, the Institute for Nuclear Chemistry, officially opened on 3 April 1967.[3][2]
In 1985 Fritz Strassmann was recognized by Yad Vashem Institute in Jerusalem as Righteous Among the Nations (חסיד אמות העולם). Together with his wife Maria (Heckter) Strassmann, he hid a Jew in their apartment, at risk to the lives of his family.[6]
Internal report
Zur Folge nach der Entstehung des 2,3 Tage-Isotops des Elements 93 aus Uran G-151 (27 February 1942) by Otto Hahn and Fritz Straßmann was published in Kernphysikalische Forschungsberichte (Research Reports in Nuclear Physics), an internal publication of the German Uranverein. Reports in this publication were classified as "Top Secret". The reports therefore had very limited distribution, and the authors were not allowed to keep copies. The reports were confiscated under the AlliedOperation Alsos and sent to the United States Atomic Energy Commission for evaluation. In 1971, the reports were declassified and returned to Germany. The reports are available at the Karlsruhe Nuclear Research Center and the American Institute of Physics.[19][20]
Further reading
Fritz Straßmann: "Über die Löslichkeit von Jod in gasförmiger Kohlensäure", Zeitschrift f. physikal. Chemie. Abt. A., Bd. 143 (1929) and PhD thesis Technical University of Hannover, 1930
Fritz Krafft: Im Schatten der Sensation. Leben und Wirken von Fritz Straßmann; Verlag Chemie, 1981
Notes
^ ab"Hitler and the Bomb". New York Times. 11 December 1988.
^O. Hahn and F. Strassmann Über den Nachweis und das Verhalten der bei der Bestrahlung des Urans mittels Neutronen entstehenden Erdalkalimetalle (On the detection and characteristics of the alkaline earth metals formed by irradiation of uranium with neutrons), Naturwissenschaften Volume 27, Number 1, 11-15 (1939). The authors were identified as being at the Kaiser-Wilhelm-Institut für Chemie, Berlin-Dahlem. Received 22 December 1938.
^O. R. Frisch Physical Evidence for the Division of Heavy Nuclei under Neutron Bombardment, Nature, Volume 143, Number 3616, 276-276 (18 February 1939)Archived 23 January 2009 at the Wayback Machine. The paper is dated 17 January 1939. [The experiment for this letter to the editor was conducted on 13 January 1939; see Richard Rhodes The Making of the Atomic Bomb 263 and 268 (Simon and Schuster, 1986).]
^Scientific and Technology Division, Library of Congress (1967). Astronautics and Aeronautics. Washington, D.C.: Scientific and Technical Information Branch, National Aeronautics and Space Administration. p. 259.
^Walker, Mark (1993). German national socialism and the quest for nuclear power, 1939-1949 (1st pbk. ed.). Cambridge University Press. pp. 268–274. ISBN0-521-43804-7.
