Greigite is an ironsulfide mineral with the chemical formula Fe2+Fe3+2S4. It is the sulfur equivalent of the iron oxide magnetite (Fe3O4). It was first described in 1964 for an occurrence in San Bernardino County, California, and named after the mineralogist and physical chemist Joseph W. Greig (1895–1977).[4][5]
Common impurities include Cu, Ni, Zn, Mn, Cr, Sb and As.[3] Ni impurities are of particular interest because the structural similarity between Ni-doped greigite and the (Fe,Ni)S clusters present in biological enzymes has led to suggestions that greigite or similar minerals could have acted as catalysts for the origin of life.[7] In particular, the cubic Fe4S4 unit of greigite is found in the Fe4S4 thiocubane units of proteins of relevance to the acetyl-CoA pathway.
Crystal structure
Greigite has the spinel structure. The crystallographic unit cell is cubic, with space group Fd3m. The S anions form a cubic close-packed lattice, and the Fe cations occupy both tetrahedral and octahedral sites.[2][8]
Magnetic and electronic properties
Like the related oxide magnetite (Fe3O4), greigite is ferrimagnetic, with the spin magnetic moments of the Fe cations in the tetrahedral sites oriented in the opposite direction as those in the octahedral sites, and a net magnetization. It is a mixed-valence compound, featuring both Fe(II) and Fe(III) centers in a 1:2 ratio. Both metal sites have high spin quantum numbers. The electronic structure of greigite is that of a half metal.[9][10]
^ abcdAnthony, John W.; Bideaux, Richard A.; Bladh, Kenneth W.; Nichols, Monte C., eds. (1990). "Greigite"(PDF). Handbook of Mineralogy. Vol. I (Elements, Sulfides, Sulfosalts). Chantilly, VA, US: Mineralogical Society of America. ISBN0962209708. Retrieved December 5, 2011.
