Larry Curtiss
Alma materUniversity of Wisconsin-Madison (BA), Carnegie-Mellon University (PhD)
OccupationChemist
Organization(s)Argonne National Laboratory, Joint Center for Energy Storage Research, the Center for Electrochemical Energy Science, American Association for the Advancement of Science
Known forGaussian-n series, lithium-air batteries
AwardsUniversity of Chicago Distinguished Performance Award
Websitewww.anl.gov/profile/larry-a-curtiss

Larry A. Curtiss is an American chemist and researcher. He was born in Madison. WI. in 1947. He is a distinguished fellow and group leader of the Molecular Materials Group in the Materials Science Division at the U.S. Department of Energy's (DOE) Argonne National Laboratory.[1] In addition, Curtiss is a senior investigator in the Joint Center for Energy Storage Research (JCESR), a DOE Energy Storage Hub, and was the deputy director of the Center for Electrochemical Energy Science, a DOE Energy Frontier Research Center.[1]

Curtiss is a specialist in developing quantum chemical methods for accurate energy calculations and applying these methods to energy- and material-related problems, including those related to catalysis, batteries, and carbon materials. His work has been cited over 67,000 times.[2]

Curtiss is a fellow of the American Association for the Advancement of Science.[3]

Early life and education

Curtiss received his bachelor's degree in chemistry from the University of Wisconsin-Madison in 1969.[1] He then attended Carnegie-Mellon University, where he completed his master's in physical chemistry in 1971, and his Ph.D. in physical chemistry in 1973.[1][4] While a graduate student, he worked under the supervision of pioneering chemist Sir John Anthony Pople, who won the Nobel Prize in chemistry for his work on computational methods in quantum chemistry.[5] Curtiss's thesis focused on quantum chemical studies of hydrogen bonded complexes. After graduating in 1973, he became a research fellow at Battelle Memorial Institute in Columbus, Ohio until 1976.[1][4]

Curtiss joined Argonne in 1976 as a research associate in Argonne's former Chemical Technology Division, where he rose through the ranks to become senior scientist in 1988.[4] In 1998, Curtiss was appointed to his current position as senior scientist and group leader of the Molecular Materials Group within Argonne's Materials Science Division.[4] From 2006 until 2009, he was also an acting group leader at the Center for Nanoscale Materials, and from 2004 until 2018, Curtiss was a senior fellow of the University of Chicago/Argonne Computation Institute.[4] In 2000, Curtiss was named an Argonne Distinguished Fellow.[3]

Research

Developing and applying computational chemistry methods

Curtiss helped develop the Gaussian-n series of quantum chemical methods for accurate energy calculations (G1, G2, G3, and G4 theories).[6][7][8][9] These methods are for calculating the thermochemical properties of molecules and ions.

Modeling lithium-ion batteries and beyond-lithium-ion batteries

Curtiss is also involved in developing so-called "beyond-lithium-ion" batteries, such as lithium-sulfur and lithium–air batteries. He helped create a Li-O2 battery that runs on lithium superoxide.[10][11] Curtiss and researchers from Argonne and the University of Illinois also designed a lithium-air battery that works in a natural air environment for over 700 charge and discharge cycles, surpassing previous technology.[12][13]

Honors and awards

Select Recent Publications

Patents

References

  1. ^ a b c d e "Larry A. Curtiss | Argonne National Laboratory". www.anl.gov. Retrieved 2019-12-06.
  2. ^ a b "Larry A. Curtiss - Google Scholar Citations". scholar.google.com. Retrieved 2019-10-27.
  3. ^ a b c "Argonne Distinguished Fellows | Argonne National Laboratory". www.anl.gov. Retrieved 2019-10-27.
  4. ^ a b c d e "Larry Curtiss" (PDF). Argonne National Laboratory. August 2018. Archived from the original on December 6, 2019.((cite web)): CS1 maint: unfit URL (link)
  5. ^ "Chemistry Tree - Sir John Anthony Pople". academictree.org. Retrieved 2019-12-06.
  6. ^ Pople, John A.; Head-Gordon, Martin; Fox, Douglas J.; Raghavachari, Krishnan; Curtiss, Larry A. (1989-05-15). "Gaussian-1 theory: A general procedure for prediction of molecular energies". The Journal of Chemical Physics. 90 (10): 5622–5629. Bibcode:1989JChPh..90.5622P. doi:10.1063/1.456415. ISSN 0021-9606.
  7. ^ Curtiss, Larry A.; Redfern, Paul C.; Raghavachari, Krishnan (2007-02-28). "Gaussian-4 theory". The Journal of Chemical Physics. 126 (8): 084108. Bibcode:2007JChPh.126h4108C. doi:10.1063/1.2436888. ISSN 0021-9606. PMID 17343441.
  8. ^ Curtiss, Larry A.; Raghavachari, Krishnan; Trucks, Gary W.; Pople, John A. (1991-06-01). "Gaussian-2 theory for molecular energies of first- and second-row compounds". The Journal of Chemical Physics. 94 (11): 7221–7230. Bibcode:1991JChPh..94.7221C. doi:10.1063/1.460205. ISSN 0021-9606.
  9. ^ Curtiss, Larry A.; Raghavachari, Krishnan; Redfern, Paul C.; Rassolov, Vitaly; Pople, John A. (1998-11-08). "Gaussian-3 (G3) theory for molecules containing first and second-row atoms". The Journal of Chemical Physics. 109 (18): 7764–7776. Bibcode:1998JChPh.109.7764C. doi:10.1063/1.477422. ISSN 0021-9606.
  10. ^ "Stable "superoxide" opens the door to a new class of batteries | Argonne National Laboratory". www.anl.gov. 12 January 2016. Retrieved 2019-10-27.
  11. ^ a b US 9553316, Lu, Jun; Amine, Khalil & Curtiss, Larry A et al., "Lithium-oxygen batteries incorporating lithium superoxide", published 2017-01-24, assigned to Uchicago Argonne LLC 
  12. ^ Community, Nature Research Chemistry (2018-03-25). "New design produces true lithium-air battery". Nature Research Chemistry Community. Retrieved 2019-10-27.
  13. ^ "Out of thin air | Argonne National Laboratory". www.anl.gov. 21 March 2018. Retrieved 2019-10-27.
  14. ^ Narayanan, Badri; Redfern, Paul C.; Assary, Rajeev S.; Curtiss, Larry A. (2019-08-07). "Accurate quantum chemical energies for 133 000 organic molecules". Chemical Science. 10 (31): 7449–7455. doi:10.1039/C9SC02834J. ISSN 2041-6539. PMC 6713865. PMID 31489167.
  15. ^ Pang, Quan; Shyamsunder, Abhinandan; Narayanan, Badri; Kwok, Chun Yuen; Curtiss, Larry A.; Nazar, Linda F. (September 2018). "Tuning the electrolyte network structure to invoke quasi-solid state sulfur conversion and suppress lithium dendrite formation in Li–S batteries". Nature Energy. 3 (9): 783–791. Bibcode:2018NatEn...3..783P. doi:10.1038/s41560-018-0214-0. ISSN 2058-7546. OSTI 1472132. S2CID 52825801.
  16. ^ Asadi, Mohammad; Sayahpour, Baharak; Abbasi, Pedram; Ngo, Anh T.; Karis, Klas; Jokisaari, Jacob R.; Liu, Cong; Narayanan, Badri; Gerard, Marc; Yasaei, Poya; Hu, Xuan (March 2018). "A lithium–oxygen battery with a long cycle life in an air-like atmosphere". Nature. 555 (7697): 502–506. Bibcode:2018Natur.555..502A. doi:10.1038/nature25984. ISSN 1476-4687. OSTI 1508362. PMID 29565358. S2CID 4376436.
  17. ^ Halder, Avik; Curtiss, Larry A.; Fortunelli, Alessandro; Vajda, Stefan (2018-03-21). "Perspective: Size selected clusters for catalysis and electrochemistry". The Journal of Chemical Physics. 148 (11): 110901. Bibcode:2018JChPh.148k0901H. doi:10.1063/1.5020301. ISSN 0021-9606. PMID 29566496.
  18. ^ Lu, Jun; Chen, Zonghai; Ma, Zifeng; Pan, Feng; Curtiss, Larry A.; Amine, Khalil (December 2016). "The role of nanotechnology in the development of battery materials for electric vehicles". Nature Nanotechnology. 11 (12): 1031–1038. Bibcode:2016NatNa..11.1031L. doi:10.1038/nnano.2016.207. ISSN 1748-3387. PMID 27920438.
  19. ^ Lu, Jun; Jung Lee, Yun; Luo, Xiangyi; Chun Lau, Kah; Asadi, Mohammad; Wang, Hsien-Hau; Brombosz, Scott; Wen, Jianguo; Zhai, Dengyun; Chen, Zonghai; Miller, Dean J. (January 2016). "A lithium–oxygen battery based on lithium superoxide". Nature. 529 (7586): 377–382. Bibcode:2016Natur.529..377L. doi:10.1038/nature16484. ISSN 0028-0836. PMID 26751057. S2CID 4452883.
  20. ^ Asadi, Mohammad; Kim, Kibum; Liu, Cong; Addepalli, Aditya Venkata; Abbasi, Pedram; Yasaei, Poya; Phillips, Patrick; Behranginia, Amirhossein; Cerrato, José M.; Haasch, Richard; Zapol, Peter (2016-07-29). "Nanostructured transition metal dichalcogenide electrocatalysts for CO 2 reduction in ionic liquid". Science. 353 (6298): 467–470. Bibcode:2016Sci...353..467A. doi:10.1126/science.aaf4767. ISSN 0036-8075. PMID 27471300.
  21. ^ US 9478837, Amine, Khalil; Curtiss, Larry A. & Lu, Jun et al., "Lithium air batteries having ether-based electrolytes", published 2016-10-25, assigned to Uchicago Argonne LLC 
  22. ^ US 10385032, Vajda, Stefan; Halder, Avik & Curtiss, Larry A., "Selective oxidation of propane to propylene oxide", published 2019-08-20, assigned to Uchicago Argonne LLC