Until 1993, the first syndic was the speaker of the General Council of Andorra. Below is a list of office holders from 1841 until 1993:[1]
| Name | Entered office | Left office | Party |
|---|---|---|---|
| Josep Picart | 1841 | 1847 | |
| Bonaventura Riba (acting) | 1847 | 1858 | |
| Gil Areny | 1858 | 1861 | |
| Francesc Duran | 1861 | 1865 | |
| Joaquim de Riba | 1865 | 28 May 1866 | |
| Guillem d'Areny-Plandolit | 28 May 1866 | 2 December 1867 | |
| Nicolau Duedra | 1 January 1870 | 31 December 1875 | |
| Guillem Mora | 1 January 1876 | 31 December 1877 | |
| Bonaventura Moles | 1 January 1878 | 8 December 1880 | |
| Joan Pla Calvo | 8 December 1880 | 10 March 1881 | |
| Josep Palmitjavila | 10 March 1881 | 10 June 1881 | |
| Francesc Duran | 14 July 1881 | 31 December 1883 | |
| Josep Palmitjavila | 1 January 1884 | 31 December 1885 | |
| Francesc Duran | 1 January 1886 | 16 April 1886 | |
| Francesc Maestre | 16 April 1886 | 26 March 1888 | |
| Antoni Moles | 26 March 1888 | 31 December 1897 | |
| Bonaventura Maestre | 20 November 1893[1] | 3 June 1899 | |
| Josep Calva | 3 June 1899 | 31 December 1901 | |
| Bonaventura Maestre | 1 January 1902 | 31 December 1905 | |
| Pere Moles | 1 January 1906 | 31 December 1911 | |
| Bonaventura Moles | 1 January 1912 | 17 May 1915 | |
| Pere Font | 17 May 1915 | 31 December 1917 | |
| Josep Vilanova | 1 January 1918 | 17 August 1920 | |
| Josep Grepa (acting) | 17 August 1920 | 20 October 1920 | |
| Bonaventura Villarubia | 20 October 1920 | 31 December 1923 | |
| Pere Font | 1 January 1924 | 31 December 1927 | |
| Roc Pallares[2] | 1 January 1928 | 19 August 1933 | |
| Vacant | 19 August 1933 | 18 September 1933 | |
| Pere Torres | 18 September 1933 | 21 July 1936 | |
| Francesc Molné Rogé | 21 July 1936 | 31 December 1936 | |
| Francesc Cairat Freixes | 1 January 1937 | 31 December 1960 | |
| Julià Reig Ribó | 1 January 1961 | 30 December 1966 | |
| Francesc Escudé Ferrero | 30 December 1966 | 30 December 1972 | |
| Julià Reig Ribó | 30 December 1972 | 29 December 1978 | |
| Estanislau Sangrá Font | 29 December 1978 | 4 January 1982 | |
| Francesc Cerqueda Pasquet | 4 January 1982 | 12 January 1990 | Lauredian Union |
| Josep Maria Beal Benedico | 12 January 1990 | 15 February 1991 | Social Democratic Party |
| Albert Gelabert | 15 February 1991 | 12 April 1992 | Liberal Party of Andorra |
| Jordi Farràs Forné | 12 April 1992 | 4 May 1993 | Democratic Party |