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Neodymium bismuthide
Names
Other names
Neodymium(III) bismuthide
Identifiers
3D model (JSmol)
  • InChI=1S/Bi.Nd
    Key: VNARRZRNLSEBPY-UHFFFAOYSA-N
  • [Nd].[Bi]
Properties
BiNd
Molar mass 352.22 g/mol
Density 8.8 g/cm3
Melting point 1775°C;[1] 1900°C[2]
Related compounds
Other anions
 Neodymium(III) nitride
Neodymium(III) arsenide
Neodymium(III) phosphide
Neodymium(III) antimonide
Neodymium(III) oxide
Other cations
 PrBi
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Neodymium bismuthide is a binary inorganic compound of neodymium and bismuth with the formula NdBi. It forms crystals.

Preparation

Neodymium bismuthide can be prepared by reacting a stoichiometric amount of neodymium and bismuth at 1900°C:

Nd + Bi → NdBi

Physical properties

Neodymium bismuthide forms cubic crystals of the space group F m3m, with cell parameters a = 0.64222 nm, Z = 4 with a structure like sodium chloride.[3] The compound melts at 1900°C. [2] At a temperature of 24 K, an antiferromagnetic transition occurs in the compound.[4]

References

  1. ^ Abulkhaev V.D. (2001). "Phase digram of the neodymium-bismuth system". p. 659-662. ISSN 0044-457X. ((cite web)): Unknown parameter |Edition= ignored (|edition= suggested) (help)
  2. ^ a b Alloy Phase Diagrams. Vol. 3. 1992. ISBN 0-87170-381-5.
  3. ^ Ed. N. P. Lyakisheva (1996). State Diagrams of Binary Metal Systems. Vol. 1. Engineering. p. 992. ISBN 5-217-02688-X.
  4. ^ P. Schobinger-Papamantellos, P. Fischer, O. Vogt, E. Kaldis (1973). "Magnetic ordering of neodymium monopnictides determined by neutron diffraction" (J. Phys. C: Solid State Phys. ed.). p. 725-737. doi:10.1088/0022-3719/6/4/020. ((cite web)): Missing or empty |url= (help)CS1 maint: multiple names: authors list (link)
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