Phosphide bromides or bromide phosphides are compounds containing anions composed of bromide (Br−) and phosphide (P3−) anions. Usually phosphorus is covalently connected into more complex structures. They can be considered as mixed anion compounds. They are in the category of pnictidehalides. Related compounds include the phosphide chlorides, phosphide iodides, nitride bromides, arsenide bromides, and antimonide bromides.

List

formula system space group unit cell Å volume density comment ref
Ca2PBr cubic I43d a=5.96 Z=2 red brown [1]
Ca2PBr hexagonal R3m a=4.23 c=20.9 Z=3 [1]
Cu12P20Br10 triclinic P a = 9.886, b = 13.190, c = 14.763, α = 70.83°, β = 82.68°, γ = 80.13°, Z = 2 1786.1 [2]
Cu13P15Br12 [3]
Cu6PS5Br cubic P43m a=9.732 Z=4 921.8 4.701 red [4]
(CuBr)2P8Se3 orthorhombic Pbcm a=8.761 b=11.957 c=13.858 Z=4 1451.8 [5]
Sr2PBr cubic I43d a=9.31 Z=2 brown violet [1]
Sr2PBr hexagonal R3m a=4.44 c=22.0 Z=3 dark reddish brown [1]
Sr2P7Br cubic P213 a=9.789 Z=4 938.0 3.342 red band gap 2.1 eV [6]
Y2PBr2 rhombohedral a=3.9807 c=29.250 [7]
Ag6PS5Br cubic P43m a=10.3765 Z=4 1117.26 5.460 red [4]
Cd5P2Br4 orthorhombic Pna21 a=12.189, b=7.7080, c=13.664 [8]
Sn24P19.3Br8 [9]
Sn17Zn7P22Br8 cubic Pm3n a=10.7449 [10]
Sn24−xInxP19.2+0.2x x<16 cubic Pm3n [11]
Si30+xP16–xTe8–xBrx x = 1–6.4 cubic Pm3n a=9.9720 - 10.0405 [12]
Ba2PBr hexagonal R3m a=4.67 c=23.3 Z=3 [1]
Ba2P7Br monoclinic P21/m a=6.294 b=6.835 c=11.850 β=95.819 Z=2 507.2 3.742 orange [13]
La2PBr2 trigonal P3m1 a=4.311 c=11.000 Z=1 177.04 5.28 [7]
La3Zn4P6.6Br0.8 orthorhombic Cmcm a=4.099 b=14.229 c=20.388 Z=4 1189.0 5.290 black [14]
Eu2PBr R3m a = 4.385, c = 21.90, Z = 3 [15]
W4(PBr)Br10 monoclinic C12/m1 a=14.0933 b=10.3228 c=11.8169 β=93.906 Z=4 1715.16 dark green [16]
Hg2P3Br orthorhombic Pbcn a = 8.014, b = 8.902, c = 7.823, Z = 4 [17]
Hg7P4Br6 monoclinic P21/c a = 6.0452, b = 19.848, c = 7.5596 β = 104.214° Z=2 879.3 7.582 brown [18]
(Hg2P)2HgBr4 monoclinic P21 a=7.776 b=12.226 c=7.930 β=121.34 Z=2 643.9 7.141 discovered in 1907; bright yellow; air with light sensitive [19]
[Hg7P4Br3](SnBr3) cubic P213 a=12.490 Z=4 [20]

References

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  8. ^ M.M., Shatruk; L.N., Reshetova; A.V., Shevel'kov; B.A., Popovkin (2000). "Cd5P2Br4 - the first cadmium analogue of salts of Millon's base" [Cd5P2Br4 - the first cadmium analogue of salts of Millon's base]. Zhurnal Neorganicheskoj Khimii (in Russian). 45 (4). ISSN 0044-457X.
  9. ^ Stefanoski, S.; Reshetova, L. N.; Shevelkov, A. V.; Nolas, G. S. (July 2009). "Low-Temperature Transport Properties of Sn24P19.3Br8 and Sn17Zn7P22Br8". Journal of Electronic Materials. 38 (7): 985–989. Bibcode:2009JEMat..38..985S. doi:10.1007/s11664-008-0644-8. ISSN 0361-5235. S2CID 135898461.
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  11. ^ Reshetova, L. N.; Shevelkov, A. V. (January 2012). "Synthesis and clathrate-type crystal structure of a solid solution in the Sn-In-P-Br system". Russian Chemical Bulletin. 61 (1): 28–32. doi:10.1007/s11172-012-0004-y. ISSN 1066-5285. S2CID 95316491.
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  14. ^ Wang, Jian; Kaseman, Derrick; Lee, Kathleen; Sen, Sabyasachi; Kovnir, Kirill (2016-07-12). "Enclathration of X@La 4 Tetrahedra in Channels of Zn–P Frameworks in La 3 Zn 4 P 6 X (X = Cl, Br)". Chemistry of Materials. 28 (13): 4741–4750. doi:10.1021/acs.chemmater.6b01752. ISSN 0897-4756.
  15. ^ Hadenfeldt, C.; Held, W. (September 1986). "Darstellung, eigenschaften und kristallstruktur der Europium(ii)-phosphidhalogenide Eu2PCl, Eu2PBr und Eu2PI". Journal of the Less Common Metals (in German). 123 (1–2): 25–35. doi:10.1016/0022-5088(86)90111-6.
  16. ^ Ströbele, Markus; Eichele, Klaus; Meyer, Hans-Jürgen (2015-02-02). "Cluster Harvesting in the WBr 6 –P System". Inorganic Chemistry. 54 (3): 989–992. doi:10.1021/ic502333u. ISSN 0020-1669. PMID 25392957.
  17. ^ Shevelkov, A. V.; Dikarev, E. V.; Popovkin, B. A. (1994-07-01). Shevelkov, A. V.; Dikarev, E. V.; Popovkin, B. A. (eds.). "Helical [unk](P 1− ) chains in the structures of Hg 2 P 3 Br and Hg 2 P 3 Cl". Zeitschrift für Kristallographie - Crystalline Materials. 209 (7): 583–585. Bibcode:1994ZK....209..583S. doi:10.1524/zkri.1994.209.7.583. ISSN 2194-4946.
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