While bishop, he was the principal consecrator of:^[2]

• Vincenzo Lanfranchi, Bishop of Trivento (1660);
• Tommaso Acquaviva d'Aragona, Bishop of Bitonto (1668);
• Giuseppe Spinucci, Bishop of Penne e Atri (1668);
• Angelo Maria Ranuzzi, Titular Archbishop of Tamiathis and Apostolic Nuncio to Savoy (1668);
• Leonardo Balsarini, Titular Bishop of Philadelphia in Arabia and Coadjutor Bishop of Chios (1668);
• Sebastiano Pisani (iuniore), Bishop of Verona (1668);
• Raimondo del Pozzo, Bishop of Vieste (1668);
• Bonaventura Cavalli, Bishop of Caserta (1668);
• Fulgenzio Arminio Monforte, Bishop of Nusco (1669);
• Marcantonio Vincentini, Bishop of Foligno (1669);
• Filippo Alferio Ossorio, Bishop of Fondi (1669);
• Giovanni Antonio Geloso, Bishop of Patti (1669);
• Vincenzo Maria da Silva, Bishop of Policastro (1671);
• John Brenan (archbishop), Bishop of Waterford and Lismore (1671);
• Giacinto Libelli, Archbishop of Avignon (1673);
• Carlo Francesco Airoldi, Titular Archbishop of Edessa in Osrhoëne (1673);
• Giuseppe Pianetti, Bishop of Todi (1673);
• Pietro Francesco Orsini de Gravina, Archbishop of Manfredonia (1675);
• Gregorio Giuseppe Gaetani de Aragonia, Titular Archbishop of Neocaesarea in Ponto (1676);
• Marziale Pellegrino, Titular Archbishop of Nazareth (1677);
• Manuel de la Torre (archbishop), Archbishop of Brindisi (1677);
• Jaime de Palafox y Cardona, Archbishop of Palermo (1677);
• Giovan Donato Giannoni Alitto, Bishop of Ruvo (1680);
• Girolamo Prignano, Bishop of Satriano e Campagna (1680);
• Giovan Giorgio Mainardi, Bishop of Ripatransone (1680);
• Tiberio Muscettola, Archbishop of Manfredonia (1680); and
• Giacinto Maria Passati, Bishop of Stagno (1680).