The Stoner criterion is a condition to be fulfilled for the ferromagnetic order to arise in a simplified model of a solid. It is named after Edmund Clifton Stoner.

Stoner model of ferromagnetism

Ferromagnetism ultimately stems from Pauli exclusion. The simplified model of a solid which is nowadays usually called the Stoner model, can be formulated in terms of dispersion relations for spin up and spin down electrons,

${\displaystyle E_{\uparrow }(k)=\epsilon (k)-I{\frac {N_{\uparrow }-N_{\downarrow )){N)),\qquad E_{\downarrow }(k)=\epsilon (k)+I{\frac {N_{\uparrow }-N_{\downarrow )){N)),}$

where the second term accounts for the exchange energy, ${\displaystyle I}$ is the Stoner parameter, ${\displaystyle N_{\uparrow }/N}$ (${\displaystyle N_{\downarrow }/N}$) is the dimensionless density^{[note 1]} of spin up (down) electrons and ${\displaystyle \epsilon (k)}$ is the dispersion relation of spinless electrons where the electron-electron interaction is disregarded. If ${\displaystyle N_{\uparrow }+N_{\downarrow ))$ is fixed, ${\displaystyle E_{\uparrow }(k),E_{\downarrow }(k)}$ can be used to calculate the total energy of the system as a function of its polarization ${\displaystyle P=(N_{\uparrow }-N_{\downarrow })/N}$. If the lowest total energy is found for ${\displaystyle P=0}$, the system prefers to remain paramagnetic but for larger values of ${\displaystyle I}$, polarized ground states occur. It can be shown that for

${\displaystyle ID(E_{\rm {F)))>1}$

the ${\displaystyle P=0}$ state will spontaneously pass into a polarized one. This is the Stoner criterion, expressed in terms of the ${\displaystyle P=0}$ density of states^{[note 1]} at the Fermi energy ${\displaystyle D(E_{\rm {F)))}$.

A non-zero ${\displaystyle P}$ state may be favoured over ${\displaystyle P=0}$ even before the Stoner criterion is fulfilled.

Relationship to the Hubbard model

The Stoner model can be obtained from the Hubbard model by applying the mean-field approximation. The particle density operators are written as their mean value ${\displaystyle \langle n_{i}\rangle }$ plus fluctuation ${\displaystyle n_{i}-\langle n_{i}\rangle }$ and the product of spin-up and spin-down fluctuations is neglected. We obtain^{[note 1]}

${\displaystyle H=U\sum _{i}[n_{i,\uparrow }\langle n_{i,\downarrow }\rangle +n_{i,\downarrow }\langle n_{i,\uparrow }\rangle -\langle n_{i,\uparrow }\rangle \langle n_{i,\downarrow }\rangle ]-t\sum _{\langle i,j\rangle ,\sigma }(c_{i,\sigma }^{\dagger }c_{j,\sigma }+h.c).}$

With the third term included, which was omitted in the definition above, we arrive at the better-known form of the Stoner criterion

${\displaystyle D(E_{\rm {F)))U>1.}$