Chemical compound
Ytterbium(II) iodide is an iodide of ytterbium, with the chemical formula of YbI2. It is a yellow solid.
Preparation
Ytterbium(II) iodide can be prepared by heating ytterbium(III) iodide:[1]
![{\displaystyle \mathrm {2\ YbI_{3}\ {\xrightarrow[{}]{\Delta \ T))\ 2\ YbI_{2}\ +\ I_{2)) }](https://wikimedia.org/api/rest_v1/media/math/render/svg/88ed882619d51e7a764bfd92497e7472f991fea9)
It can also be prepared by reacting metallic ytterbium with 1,2-diiodoethane in tetrahydrofuran:[3]
![{\displaystyle \mathrm {Yb\ +\ ICH_{2}CH_{2}I\ {\xrightarrow[{}]{THF))\ YbI_{2}\ +\ H_{2}C=CH_{2)) }](https://wikimedia.org/api/rest_v1/media/math/render/svg/f6256891740045130f67f044c37eb51aed8e8f23)
Although the reaction takes place at room temperature, due to the sensitivity of the reagents it is necessary to work anhydrous and under inert gas. Otherwise, if oxygen is present, rapid oxidation to ytterbium(III) takes place. This can be visually recognized by the color change from green to yellow solution.
Properties and uses
Ytterbium(II) iodide is a yellow solid that is very sensitive to air and moisture and is rapidly oxidized to ytterbium(III). It reacts with water to produce hydrogen gas and basic iodides, and reacts violently with acids.[1] Ytterbium(II) iodide sinters at 0.01 Torr from about 780 °C and gives a viscous melt at about 920 °C. It begins to disproportionate into ytterbium and ytterbium(III) iodide. At around 800 °C, a yellow sublimate of ytterbium(II) iodide is observed on the glass walls; this partly obscures the disproportionation. The melting point can therefore only be determined imprecisely.[1][4]
Like samarium(II) iodide (SmI2), ytterbium(II) iodide is a reagent used in organic chemical reactions.[3]
