The following is an archived discussion of a featured article nomination. Please do not modify it. Subsequent comments should be made on the article's talk page or in Wikipedia talk:Featured article candidates. No further edits should be made to this page.

The article was promoted by Ealdgyth via FACBot (talk) 31 August 2020 [1].


Hassium[edit]

Nominator(s): R8R, Double sharp (talk) 14:04, 2 July 2020 (UTC)[reply]

We return once again to bring you another superheavy element, after dubnium and nihonium back in 2018, and tennessine (then ununseptium) back in 2015. After the first FAC, we did some more work on the article (chronicled on the talk page), and I think we're ready to try again now. Hopefully this is a pleasant enough read for the subject matter while we sit back and wait for element 119 to reveal itself! ^_^ Double sharp (talk) 14:04, 2 July 2020 (UTC)[reply]

Image review
Comment
@Buidhe: This was discussed at Wikipedia_talk:WikiProject_Elements#Introduction_into_superheavy_elements. The main reason is that this info is relevant to basically all the heaviest elements on the table (102 and up), but it's also basically necessary to explain how these elements are really made in practice. Unfortunately, it seems that if we change the images to float right, they float under the infobox inside the next section, which isn't really better.
@R8R: What do you think? Double sharp (talk) 15:35, 3 July 2020 (UTC)[reply]
@Double sharp: I agree that floating right isn't better. in fact, doing it so would necessitate completely rearranging all the images in the article. Maybe we could move it lower (two paragraphs or so down) in the section so that it starts after the infobox ends?
@Buidhe: +1 to Double sharp. In an earlier review, I did suggest including this introduction to provide context for more sophisticated terms, and the transfusion came about as the simplest solution to for including the same pertinent background in 17 element articles (as it is equally relevant and helpful in all of them). ComplexRational (talk) 17:29, 3 July 2020 (UTC)[reply]
My take on that unfortunately, we're stuck with this sandwiching because any other alternative is either not feasible or worse encyclopedically (if that's a word). We do need the transcluded section because we need an introduction into what people find a complicated topic; our introduction is, I believe, a great way to start reading. We also need this introduction in 16 more articles and possibly even more in the future, hence it would be great to keep it in one place which would host all edits made to it rather than let the bunch slowly get less and less synchronized. And there isn't really anywhere else to add the pictures, and they are important for illustrating the transcluded section. We do need the first picture in that section, it is of paramount encyclopedic importance there. Moving the picture down the text simply moves the problem down the text. At my screen resolution of 2560x1440 there is no cure to this sandwiching.
I'm sorry it comes out this way but the other options are worse.--R8R (talk) 18:04, 3 July 2020 (UTC)[reply]
Good point. I also realize now that the infobox is even longer in some articles, sandwiching the entire section. I'd agree it's not ideal, but the alternatives would cost a useful illustration or more serious formatting issues, so I'm inclined to leave it as is now. ComplexRational (talk) 19:26, 3 July 2020 (UTC)[reply]
Would it help if we put the image to the right, forcing it to follow any infobox? This could even be made optionally per article (using a parameter). -DePiep (talk) 12:11, 4 July 2020 (UTC)[reply]
It could exist as a parameter, but forcing these images below the infobox will (1) risk displaying the images outside their associated section (this would be even worse in articles such as rutherfordium with longer infoboxes) and (2) require rearranging all the images in the article to keep a left-right alteration. I'm not seeing a good way out. ComplexRational (talk) 13:40, 4 July 2020 (UTC)[reply]

Support from ComplexRational[edit]

I have made a few substantive edits to the article myself, but as documented in the talk page chronicles, most of my work on this article has been as a reviewer; it has been a pleasure to read and review it. It has definitely come a long way since the first FAC; it is clear and complete, does not leave burning questions, and seems much more understandable to a layperson (compared to the time of the first FAC), as much of the jargon is explained. That said, I would like to highlight a few more things before offering my support.

ComplexRational (talk) 01:22, 3 July 2020 (UTC)[reply]

I'm sorry, I genuinely don't remember us discussing this before.--R8R (talk) 14:33, 7 July 2020 (UTC)[reply]
The 2019 estimate might be a better place to start if you believe it's a good idea. I feel it's already emphasized that several experiments were performed, and it seems clear to me (but maybe not all readers) the contrast between the amount of research done on hassium vs. all heavier elements (as noted in their respective articles). And you're right, I don't think we discussed it. I removed it in this edit, which I surprisingly remember, and was genuinely convinced I did it much more recently than December 2018. I still feel the same way about it now, though, but I'm open to a less crude estimate to give a general idea if there is a recent source available. ComplexRational (talk) 14:57, 7 July 2020 (UTC)[reply]
I've put in the two references I mentioned above and modified the sentence somewhat. Does it look good for you?--R8R (talk) 21:05, 9 July 2020 (UTC)[reply]
This looks better. It leaves room to account for what I mentioned, and you're right that if there were over 1,000 atoms, the word choice would reflect that (rather than simply over 100). Also, for future reference, we say "on the order of" rather than "in the order of"; I made that correction. More English language peculiarities... anyway, I think we can consider this resolved. I'll review the rest of the comments hopefully tomorrow or over the weekend. ComplexRational (talk) 23:18, 9 July 2020 (UTC)[reply]
Thanks for the tip; I think you mentioned it to me some time before but evidently I may not always be the fastest learner.
I'll gladly wait for your upcoming responses.--R8R (talk) 20:53, 10 July 2020 (UTC)[reply]
@R8R: All done. RL has been quite a mess and mentally very taxing this week, so I apologize for not finishing sooner. I have one open comment still, and would like to resolve that, but this article has come a long way over the past year and with all the changes enacted, I'm happy to support now. ComplexRational (talk) 21:53, 17 July 2020 (UTC)[reply]
@ComplexRational: thank you very much! There's no problem with waiting whatsoever since I'm not active every day, too. I hope you're doing fine. I took another look at the last issue you raised and I think I found a good solution.--R8R (talk) 11:05, 19 July 2020 (UTC)[reply]

Support from Hurricanehink[edit]

Support - I came here from an FAC I'm co-nomming, hoping you might be able to review it if you have the time. Alright, elements! Here we go.

All in all, the article is pretty technical, but for an element that none of will ever touch or interact with, I'm glad that you were so thorough in your research, so I could read all about it. ♫ Hurricanehink (talk) 20:06, 3 July 2020 (UTC)[reply]

Thank you very much. I hope your read wasn't overwhelming; the topic is indeed quite technical but I generally strive to write in a manner that is as accessible to everyone as possible. I'll try to review your article during the next week; if I haven't done so by the end of it, please feel free to point that out to me.--R8R (talk) 09:19, 5 July 2020 (UTC)[reply]
Could you add those sources in then? If the sources are in the table, could you just re-add it to the prose? I always look out for any paragraph that doesn't end in a source. Also, one last thing I thought of. Is there any estimate for how much Hassium has ever been produced? You mention in the lead "minuscule quantities", but I don't see where in the article you specify that amount. ♫ Hurricanehink (talk) 14:48, 5 July 2020 (UTC)[reply]
Am I correct in understanding that you mean re-adding the reference for the first point you raise?
Correct. I notice a few sections that don't have any citations at the end: 2nd paragraph of "Cold fusion", 2nd and 3rd paragraph of "Isotopes", and the 5th paragraph of "natural occurrence", which... I noticed "No results have been released." IDK what's appropriate for chemistry articles, but maybe add a "As of ((currentyear))" in this sentence? Tough to cite a negative though. ♫ Hurricanehink (talk) 15:40, 7 July 2020 (UTC)[reply]
As for lack of citations at the end of paragraphs: I have generally applied my common sense and the Wikipedia policy (luckily, the two coincide): I put citations wherever the information could actually be challenged by a curious reader. I generally doubt it that somebody is actually going to question the nomenclature (as in the 2nd paragraph of "Cold fusion") when the physics behind it is cited. Sometimes, paragraphs end on statements that I expand on in the following paragraphs (2nd paragraph of "Isotopes"). The sentence ending the 3rd paragraph of "Isotopes" is referenced, it's just the references for the convenience of a curious reader willing to check the sources are not at the end of the sentence. As for the 5th paragraph of "natural occurrence", it is indeed hard to cite a negative but luckily there's something coming our way, so I'll expand on this statement regardless of whether the report has actually been released.--R8R (talk) 20:34, 9 July 2020 (UTC)[reply]
I have reworked the 5th paragraph of "natural occurrence," so that's now out of the way too.--R8R (talk) 20:44, 10 July 2020 (UTC)[reply]
There is one vague estimate which has been reproduced a few times. I don't know the ultimate origin of the estimate (the book I found it in doesn't use in-line citations) but it's rather believable. Added it in the beginning of the Isotopes section.--R8R (talk) 20:19, 6 July 2020 (UTC)[reply]
I appreciate that bit, but could you improve the wording of the bolded part - "As of 2011, only "more than 100 atoms" of hassium have been produced" - grammatically it could be stronger. For instance, "As of 2011, the amount of Hassium atoms ever produced numbered in the hundreds." I hope that still implies the same meaning, and it could still be written stronger. It's a shame the source wasn't more specific, like giving a range, or giving some cap. More than 100 could be 1,000 or a million, which is different when it comes to microscopic quantities. ♫ Hurricanehink (talk) 15:40, 7 July 2020 (UTC)[reply]
I went for the time being for "As of 2019, the quantity of all hassium ever produced was in the order of hundreds of atoms." This seems good enough for me. I frankly rather doubt it that anyone would assume that if it there were a few thousands of atoms that anyone would mention merely "more than 100". That is mathematically correct but that's not how real language usually works :) but the combination of sources makes me even more confident in the statement as I gave it.--R8R (talk) 20:34, 9 July 2020 (UTC)[reply]
Readded the particular source citing the sentence.--R8R (talk) 20:35, 9 July 2020 (UTC)[reply]
Thanks! Your wording for "hundreds" works great.I'm picky, and for all of the hard work you've put into it, you should be proud of what you've written (with other writers, yea, Wikipedia is a collaborative platform, but I know what it's like doing the bulk of the work for a very niche subject, and as a fellow science nerd, I appreciate your work on such an elementary article). Happy to support. ♫ Hurricanehink (talk) 01:23, 10 July 2020 (UTC)[reply]
Thank you very much! Most elements are not as niche, but it's good to branch out every once in a while. I should be able to start a review on your article on Sunday.--R8R (talk) 20:44, 10 July 2020 (UTC)[reply]

Comments from profdc9[edit]

As atomic number increases, so does the electrostatic attraction between an electron and the nucleus. This causes the velocity of the electron to increase, which leads to an increase its mass. This in turn increases the gravitational attraction between the electron and the nucleus I do not believe the description of the change in the interaction due to the relativistic velocities of the inner shell electrons should be described as gravitational attraction. Gravity (in so far as is known) is a separate force from the electromagnetic interaction binding electrons to the nucleus. Gravity is many orders of magnitude smaller in strength than the electromagnetic force and so gravity plays essentially no significant role in determining the electronic structure of any atom. The effect being considered, the relativistic increase in mass-energy of the electron as it approaches light speed, is an effect known in special relativity and does not the require gravitational considerations of general relativity. That said, whether or not the relativistic trends of the lanthanide group persist or not in the actinide group, is outside of my expertise, with the increased screening of s and p orbitals resulting in higher electron affinities for actinides than lanthanides, as mentioned stabilizing the +8 oxidation further of hassium over osmium, though this summary seems to suggest such effects. [1]

Indeed. Thank you very much for taking your time to write this comment. As I was writing that, I was rather confused myself about why greater mass would play a role anyway. Your comment prompted me to look it up, and I got it now. Please see if it's good enough now.--R8R (talk) 09:01, 5 July 2020 (UTC)[reply]

References

Comments from DePiep[edit]

About actual proposed section names: I understand you mention E102 and E103, nobelium and lawrencium, because they are not 'superheavy' (a definition not clarified nearby, that is: a reader might easily miss this detail—as I do. Doesn't this say the wording, trying to define it, is unfit for all 16 articles?).
I'd prefer a short, crisp sectiontitle, aimed at the TOC, not detailed; no need to put the excact definition of 'heavy' or 'superheavy' in this sectiontitle. I prefer like Introduction to [super]heavy elements. -DePiep (talk) 18:51, 4 July 2020 (UTC)[reply]
To clarify my preference: I prefer any of the two proposed here (not using [ ] brackets); actual choice should be short, but in no way incorrect or confusing (up to the specialists). Changing between the transcluding articles may occur AFAIK. -DePiep (talk) 10:51, 8 July 2020 (UTC)[reply]
 Introduction to the heaviest elements
 Introduction to superheavy elements
So since Double sharp also likes this idea, I'll change the title to "Introduction to the heaviest elements" for the time being, although if you have another reason to have a different title, I'll gladly consider it.--R8R (talk) 19:57, 9 July 2020 (UTC)[reply]
Now that I've made the change, the longer title seems rather clumsy but we can live with that if considering the lead section an introduction is actually a thing.--R8R (talk) 20:01, 9 July 2020 (UTC)[reply]
The lede, I suppose, is more of a summary than an introduction. OTOH, whenever you have some stuff before a bunch of level-3 sections, then I can see a sort of quasi-lede being used as an introduction. Anyway, I like what we have now ("Introduction to the heaviest elements") because it tells us what we're going to get in that section. Double sharp (talk) 05:46, 11 July 2020 (UTC)[reply]
Afternote: I find the notion that the original "Introduction" it can rightly be read as "Introduction to hassium" incorrect. That is not the content of the section. Also, the original source article title also so. -DePiep (talk) 17:56, 14 July 2020 (UTC)[reply]
I conclude consensus for the change. This also implies the same change for the other transcluding element articles. -DePiep (talk) 18:26, 16 July 2020 (UTC)[reply]
I'm fine with that. Double sharp (talk) 15:10, 17 July 2020 (UTC)[reply]
1. The introduction The chemical element with the highest atomic number ... by observation in nature (4 sentences) is only about the general Z=A+N description. I don't think this is needed. By now and by here in the article, concepts of "heavy" and "atomic number" should be clear. First suggestion: remove those [four senteces], and adjust next sentence.
Sorry to say this, that's not what those sentences are about. They are about what the heaviest element in the nature is (from what point discoveries by synthesis begin). There is no mention of N or A whatsoever. Another point is to introduce the "element XX" terminology which the general reader may be unfamiliar with. Removing those sentences would make the text less readable as per what I just mentioned.--R8R (talk) 09:31, 18 July 2020 (UTC)[reply]
2. Why this section at all? An old introduction to the transfermium wars that was kept? It has nothing to do with hassium, and does not even make an introduction to it (or its discoverers). Also, to me it occurred as an extension/protraction of sorts to the previous section. What would the article lack when we remove this section? -DePiep (talk) 19:57, 16 July 2020 (UTC)[reply]
There are two main stories to uncover in history of discovery of an element such as hassium: one is that there is a great amount of technological/scientific developments that are needed for the discovery, and the discovery is a scientific achievement regardless of who achieves it. The other story is that there are different scientific teams seeking to write themselves down in history as discoverers. This subsection is an introduction to the latter story (and the next one introduces the reader to the former). This section ends on the very important idea that there is this conflict and that other teams are a part of this. Even though the lab in Berkeley did not claim discovery of element 108, it is still important because its other claims clashed with the German claim to the displeasure of both the Americans and the Germans.--R8R (talk) 09:31, 18 July 2020 (UTC)[reply]
1. Another pre-discovery section, and an overall generic introduction. It does not specifically lead to 108. My first idea is to merge relevant parts into the actual discovery-of-hassium section.
I beg to differ, it is very relevant and not generic. The cold fusion technology was only useful for discoveries of a limited number of elements (107 through 113). And it's important because even though you can figure out that 88 + 20 = 108 or 82 + 26 = 108 (those reactions are mentioned in the reports section), if you want to really understand the subject you need to know why those were the combinations used and not, say, 96 + 12 = 108.--R8R (talk) 09:31, 18 July 2020 (UTC)[reply]
2. The section Hassium#Reports does describe the actual discovery. For this, its title is a bit understating. Maybe the cold fusion + and reports (process of discovedry and claim) could make a strong centerpiece of #Discovery. -DePiep (talk) 19:57, 16 July 2020 (UTC)[reply]
I really do give a positive answer to at least something but I find myself unable to do so. I think "Reports" is a solid title. That you report a discovery and that you think you have made a discovery doesn't mean you have, and any discovery needs a confirmation. Arbitration is a fairly short section because it would otherwise be too technical. Naming is an important section, not scientifically but symbolically: as in any human endeavor, there are people whose feelings are an important part of the picture: in this case, the feelings in question are the desire to discover something new and be the first to do so and the desire to get recognized for it.
If you think there's anything important missing, I'm all ears. A comment like "maybe it could make a strong centerpiece" is hard to react to especially when I think it already is already satisfied.
There are important things about a discovery other than the experiment itself. I think I covered them all. If you think otherwise, again, I'll be glad to consider that.
Also, since you knew this article would be at a FAC, I would've appreciated it if you had made your big content comments before the process started. I hope we can make this a common practice in the future.--R8R (talk) 09:31, 18 July 2020 (UTC)[reply]
I'll try to respond tonight.--R8R (talk) 14:17, 17 July 2020 (UTC)[reply]
Ah, alas I can't do it today, but I have an answer in mind and I'll try to write it down tomorrow.--R8R (talk) 18:11, 17 July 2020 (UTC)[reply]
How are things here now? DePiep, did you have anything to add? Cheers, Ian Rose (talk) 23:45, 7 August 2020 (UTC)[reply]

Support from Naypta[edit]

I've not conducted a broad review of sources for the statements here, I'm mostly focusing on the prose and text.

In the case of this particular article, these clarifications are also useful because they serve as a subtle hint to the names mentioned in note n.--R8R (talk) 17:59, 25 July 2020 (UTC)[reply]
If I may, can I suggest we leave it as it is and then re-negotiate this title problem at WT:ELEM when this FAC is over? This seems like such a small problem that is to be re-negotiated anyway--R8R (talk) 19:03, 28 July 2020 (UTC)[reply]
I've struck this point on these lines - not because I don't think it's an issue, but on the basis of venue. Naypta ☺ | ✉ talk page | 13:49, 1 August 2020 (UTC)[reply]

Hopefully that makes some semblance of sense! Naypta ☺ | ✉ talk page | 20:27, 21 July 2020 (UTC)[reply]

Hi! Thank you for dropping by, I will try to respond today.--R8R (talk) 10:02, 25 July 2020 (UTC)[reply]
@Naypta: I have responded to most of your comments. Your comments have been great: I particularly like getting comments from people who are not very familiar with the subject at hand very well because such people tend to look at a text differently, and they can spot some things I can't. I hope your read wasn't too overwhelming, at least the first couple of sections. Thank you very much for your comments!--R8R (talk) 17:59, 25 July 2020 (UTC)[reply]
@R8R: Cheers! Some thoughts above where appropriate. Naypta ☺ | ✉ talk page | 23:08, 26 July 2020 (UTC)[reply]
@Naypta: may I ask you to strike those comments you consider resolved? It would help enormously to keep track of those comments that are yet to be resolved.--R8R (talk) 16:12, 28 July 2020 (UTC)[reply]
R8R Sorted, cheers! Naypta ☺ | ✉ talk page | 16:30, 28 July 2020 (UTC)[reply]

@Naypta: I have responded to the rest of your comments. I did as advised with two exceptions: I kept the long location format after my co-nominator Double sharp has come along and said he was in favor of keeping them in this particular article, and suggested we leave the "Introduction" vs. Introduction to the heaviest elements" debate for a later discussion at WT:ELEM. Can I consider at this point I have resolved all issues you raised, or do you disagree or have any more comments?--R8R (talk) 09:11, 31 July 2020 (UTC)[reply]

@R8R: Looks good! Happy to support :) Naypta ☺ | ✉ talk page | 13:49, 1 August 2020 (UTC)[reply]

HaEr48 (support)[edit]

Will review this in the next few days. HaEr48 (talk) 03:23, 13 August 2020 (UTC)[reply]

@R8R: Suggest explaining in terms of high speed/similar, which is easier to grasp for a beginner reader than "this effect is relativistic". HaEr48 (talk) 05:21, 26 August 2020 (UTC)[reply]
@HaEr48: did you see note y that I added yesterday?
Generally, the easy way to explain this would be to say that according to the special theory of relativity, both electric fields and magnetic fields are not separate but rather different appearances of common electromagnetic fields; depending on the frame of reference, an electromagnetic field can be more or less electric and more or less magnetic. A magnetic field can only interact with a magnetic field, not with an electric field, but depending on your frame of reference, the electric field can also be a magnetic field. The magnetic field I'm talking about here is the field created by the spin of an electron and the electric field is created by the charge of the nucleus; from the frame of reference tied to the electron, it can be also seen as a magnetic field. There you have two magnetic fields which interact, and that's what the spin--orbit interaction is.
I placed that note where I did in order to cover the splitting in the same note, and I couldn't do it before I had introduced the splitting in that paragraph. If you think that note y needs any corrections, clarification, etc., I'm all ears.--R8R (talk) 10:50, 26 August 2020 (UTC)[reply]
Hello, HaEr48. I always write with common readers in mind, so a thorough read by a non-specialist is very welcome. You can definitely claim your points for this review, they are well deserved; I genuinely enjoy feedback like this review. I will try to start to respond to it tonight.—R8R (talk) 14:40, 15 August 2020 (UTC)[reply]
The look labels I have added are meant to be notes for self.--R8R (talk) 10:28, 16 August 2020 (UTC)[reply]
I added blue for my remaining actionable feedback. The rest looks good. HaEr48 (talk) 03:13, 23 August 2020 (UTC)[reply]
Support This is a very well-written article on a difficult topic, and the author have responded positively to all my feedbacks. I might still have minor questions about the spin-orbit splitting, but I'll discuss that outside this FAC. HaEr48 (talk) 14:09, 27 August 2020 (UTC)[reply]

WereSpielChequers query Support[edit]

Hi, I don't understand "The combination of the two leads to that the". If it makes sense to experts, is there a way of rephrasing it for the rest of us? Similarly "The lightest isotopes, which usually have shorter half-lives,[u] as well as the most were synthesized by direct fusion between two lighter nuclei and as decay products." begs the question, Most what? ϢereSpielChequers 22:25, 27 August 2020 (UTC)[reply]

Hi. I agree, those two are very clumsy wordings. I changed the former to "As a result of the combination of the direct and indirect relativistic effects". As for the latter, two words went missing at some point, and the sentence wasn't that good to begin with, so I simplified it to "Lighter isotopes were usually synthesized by direct fusion between two lighter nuclei, whereas heavier isotopes were typically observed as decay products of nuclei with larger atomic numbers."--R8R (talk) 12:59, 28 August 2020 (UTC)[reply]
Thanks, those changes work for me. Another question, I appreciate that small sample sizes make it difficult to measure half lives, but if there have been multiple differing measurements of the half lives are you sure we should take the latest measurement as opposed to quoting differing measurements by different scientists? If the data is pooled and differing measurements are due to more recent ones being drawn from more data, then perhaps the article could say that, and of course in that case latest measures and confidence levels make sense. ϢereSpielChequers 14:19, 29 August 2020 (UTC)[reply]
@WereSpielChequers: I don't recall exactly for the sources cited here, but in general, the more recent publications give values based on all the experimental data (including past experiments) rather than only the one described in the paper. That is indeed what gives rise to a difference, and makes the more recent values preferable. The only other difference I could see is that different publications express uncertainty differently. NUBASE gives a symmetrical error margin (a ± b), whereas most others give a 68% confidence interval (corresponding to an error of 1σ) derived directly from the combined dataset. (I presume there is not enough data to reliably use a wider confidence interval.) I chose to include both to avoid confusion from differing approaches or inconsistent datasets, but if you believe this difference in expression (symmetrical vs. 1σ) should be highlighted in a footnote, that can be done. ComplexRational (talk) 15:23, 29 August 2020 (UTC)[reply]
Thanks, that makes sense. Shifting to Support as an interesting and informative article. I've also proposed it as a suitable metal for one of our service awards. ϢereSpielChequers 15:35, 29 August 2020 (UTC)[reply]

Coord note[edit]

Looks like we need a source review? And DePiep can you revisit? --Ealdgyth (talk) 14:27, 15 August 2020 (UTC)[reply]

Source review - spotchecks not done

@Nikkimaria: do you think I have addressed all points you raised?--R8R (talk)

Good enough. Nikkimaria (talk) 21:22, 29 August 2020 (UTC)[reply]
The above discussion is preserved as an archive. Please do not modify it. No further edits should be made to this page.