Classical thermodynamics considers three main kinds of thermodynamic processes: (1) changes in a system, (2) cycles in a system, and (3) flow processes.

(1) A Thermodynamic process is a process in which the thermodynamic state of a system is changed. A change in a system is defined by a passage from an initial to a final state of thermodynamic equilibrium. In classical thermodynamics, the actual course of the process is not the primary concern, and often is ignored. A state of thermodynamic equilibrium endures unchangingly unless it is interrupted by a thermodynamic operation that initiates a thermodynamic process. The equilibrium states are each respectively fully specified by a suitable set of thermodynamic state variables, that depend only on the current state of the system, not on the path taken by the processes that produce the state. In general, during the actual course of a thermodynamic process, the system may pass through physical states which are not describable as thermodynamic states, because they are far from internal thermodynamic equilibrium. Non-equilibrium thermodynamics, however, considers processes in which the states of the system are close to thermodynamic equilibrium, and aims to describe the continuous passage along the path, at definite rates of progress.

As a useful theoretical but not actually physically realizable limiting case, a process may be imagined to take place practically infinitely slowly or smoothly enough to allow it to be described by a continuous path of equilibrium thermodynamic states, when it is called a "quasi-static" process. This is a theoretical exercise in differential geometry, as opposed to a description of an actually possible physical process; in this idealized case, the calculation may be exact.

A really possible or actual thermodynamic process, considered closely, involves friction. This contrasts with theoretically idealized, imagined, or limiting, but not actually possible, quasi-static processes which may occur with a theoretical slowness that avoids friction. It also contrasts with idealized frictionless processes in the surroundings, which may be thought of as including 'purely mechanical systems'; this difference comes close to defining a thermodynamic process.[1]

(2) A cyclic process carries the system through a cycle of stages, starting and being completed in some particular state. The descriptions of the staged states of the system are not the primary concern. The primary concern is the sums of matter and energy inputs and outputs to the cycle. Cyclic processes were important conceptual devices in the early days of thermodynamical investigation, while the concept of the thermodynamic state variable was being developed.

(3) Defined by flows through a system, a flow process is a steady state of flows into and out of a vessel with definite wall properties. The internal state of the vessel contents is not the primary concern. The quantities of primary concern describe the states of the inflow and the outflow materials, and, on the side, the transfers of heat, work, and kinetic and potential energies for the vessel. Flow processes are of interest in engineering.

Kinds of process

Cyclic process

Defined by a cycle of transfers into and out of a system, a cyclic process is described by the quantities transferred in the several stages of the cycle. The descriptions of the staged states of the system may be of little or even no interest. A cycle is a sequence of a small number of thermodynamic processes that indefinitely often, repeatedly returns the system to its original state. For this, the staged states themselves are not necessarily described, because it is the transfers that are of interest. It is reasoned that if the cycle can be repeated indefinitely often, then it can be assumed that the states are recurrently unchanged. The condition of the system during the several staged processes may be of even less interest than is the precise nature of the recurrent states. If, however, the several staged processes are idealized and quasi-static, then the cycle is described by a path through a continuous progression of equilibrium states.

Flow process

Defined by flows through a system, a flow process is a steady state of flow into and out of a vessel with definite wall properties. The internal state of the vessel contents is not the primary concern. The quantities of primary concern describe the states of the inflow and the outflow materials, and, on the side, the transfers of heat, work, and kinetic and potential energies for the vessel. The states of the inflow and outflow materials consist of their internal states, and of their kinetic and potential energies as whole bodies. Very often, the quantities that describe the internal states of the input and output materials are estimated on the assumption that they are bodies in their own states of internal thermodynamic equilibrium. Because rapid reactions are permitted, the thermodynamic treatment may be approximate, not exact.

A cycle of quasi-static processes

Main article: Stirling cycle

An example of a cycle of idealized thermodynamic processes which make up the Stirling cycle

A quasi-static thermodynamic process can be visualized by graphically plotting the path of idealized changes to the system's state variables. In the example, a cycle consisting of four quasi-static processes is shown. Each process has a well-defined start and end point in the pressure-volume state space. In this particular example, processes 1 and 3 are isothermal, whereas processes 2 and 4 are isochoric. The PV diagram is a particularly useful visualization of a quasi-static process, because the area under the curve of a process is the amount of work done by the system during that process. Thus work is considered to be a process variable, as its exact value depends on the particular path taken between the start and end points of the process. Similarly, heat may be transferred during a process, and it too is a process variable.

Conjugate variable processes

It is often useful to group processes into pairs, in which each variable held constant is one member of a conjugate pair.

Pressure – volume

The pressure–volume conjugate pair is concerned with the transfer of mechanical energy as the result of work.

Temperature – entropy

The temperature-entropy conjugate pair is concerned with the transfer of energy, especially for a closed system.

Chemical potential - particle number

The processes just above have assumed that the boundaries are also impermeable to particles. Otherwise, we may assume boundaries that are rigid, but are permeable to one or more types of particle. Similar considerations then hold for the chemical potentialparticle number conjugate pair, which is concerned with the transfer of energy via this transfer of particles.

Thermodynamic potentials

Any of the thermodynamic potentials may be held constant during a process. For example:

Polytropic processes

Main article: Polytropic process

A polytropic process is a thermodynamic process that obeys the relation:

where P is the pressure, V is volume, n is any real number (the "polytropic index"), and C is a constant. This equation can be used to accurately characterize processes of certain systems, notably the compression or expansion of a gas, but in some cases, liquids and solids.

Processes classified by the second law of thermodynamics

According to Planck, one may think of three main classes of thermodynamic process: natural, fictively reversible, and impossible or unnatural.[2][3]

Natural process

Only natural processes occur in nature. For thermodynamics, a natural process is a transfer between systems that increases the sum of their entropies, and is irreversible.[2] Natural processes may occur spontaneously upon the removal of a constraint, or upon some other thermodynamic operation, or may be triggered in a metastable or unstable system, as for example in the condensation of a supersaturated vapour.[4] Planck emphasised the occurrence of friction as an important characteristic of natural thermodynamic processes that involve transfer of matter or energy between system and surroundings.

Effectively reversible process

To describe the geometry of graphical surfaces that illustrate equilibrium relations between thermodynamic functions of state, no one can fictively think of so-called "reversible processes". They are convenient theoretical objects that trace paths across graphical surfaces. They are called "processes" but do not describe naturally occurring processes, which are always irreversible. Because the points on the paths are points of thermodynamic equilibrium, it is customary to think of the "processes" described by the paths as fictively "reversible".[2] Reversible processes are always quasistatic processes, but the converse is not always true.

Unnatural process

Unnatural processes are logically conceivable but do not occur in nature. They would decrease the sum of the entropies if they occurred.[2]

Quasistatic process

Main article: Quasistatic process

A quasistatic process is an idealized or fictive model of a thermodynamic "process" considered in theoretical studies. It does not occur in physical reality. It may be imagined as happening infinitely slowly so that the system passes through a continuum of states that are infinitesimally close to equilibrium.

See also


  1. ^ Reiss, H. (1965). Methods of Thermodynamics, Blaisdell, New York, page 52: "The frictionless systems may be referred to as purely mechanical systems whereas those with friction are thermodynamic systems."
  2. ^ a b c d Guggenheim, E.A. (1949/1967). Thermodynamics. An Advanced Treatment for Chemists and Physicists, fifth revised edition, North-Holland, Amsterdam, p. 12.
  3. ^ Tisza, L. (1966). Generalized Thermodynamics, M.I.T. Press, Cambridge MA, p. 32.
  4. ^ Planck, M.(1897/1903). Treatise on Thermodynamics, translated by A. Ogg, Longmans, Green & Co., London, p. 82.

Further reading