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The decay energy is the energy change of a nucleus having undergone a radioactive decay. Radioactive decay is the process in which an unstable atomic nucleus loses energy by emitting ionizing particles and radiation. This decay, or loss of energy, results in an atom of one type (called the parent nuclide) transforming to an atom of a different type (called the daughter nuclide).

Decay calculation

The energy difference of the reactants is often written as Q:

[1]

Decay energy is usually quoted in terms of the energy units MeV (million electronvolts) or keV (thousand electronvolts):

[2]

Types of radioactive decay include

The decay energy is the mass difference Δm between the parent and the daughter atom and particles. It is equal to the energy of radiation E. If A is the radioactive activity, i.e. the number of transforming atoms per time, M the molar mass, then the radiation power P is:

or

or

Example: 60Co decays into 60Ni. The mass difference Δm is 0.003 u. The radiated energy is approximately 2.8 MeV. The molar weight is 59.93. The half life T of 5.27 year corresponds to the activity A = N [ ln(2) / T ], where N is the number of atoms per mol, and T is the half-life. Taking care of the units the radiation power for 60Co is 17.9 W/g

Radiation power in W/g for several isotopes:

60Co: 17.9
238Pu: 0.57
137Cs: 0.6
241Am: 0.1
210Po: 140 (T = 136 d)
90Sr: 0.9
226Ra: 0.02

For use in radioisotope thermoelectric generators high decay energy combined with a long half life is desirable. To reduce the cost and weight of radiation shielding, sources that do not emit strong gamma radiation are preferred. This table gives an indication why - despite its enormous cost - 238
Pu
with its roughly eighty year half life and low gamma emissions has become the RTG nuclide of choice. 90
Sr
performs worse than 238
Pu
on almost all measures, being shorter lived, a beta emitter rather than an easily shielded alpha emitter and releasing significant gamma radiation when its daughter nuclide 90
Y
decays, but as it is a high yield product of nuclear fission and easy to chemically extract from other fission products, Strontium titanate based RTGs were in widespread use for remote locations during much of the 20th century. Cobalt-60 while widely used for purposes such as food irradiation is not a practicable RTG isotope as most of its decay energy is released by gamma rays, requiring substantial shielding. Furthermore its five year half life is too short for many applications.

See also

References

  1. ^ "Alpha Decay" (PDF). Soton. Archived (PDF) from the original on 2016-05-08. Retrieved 31 March 2021.
  2. ^ Choppin, Gregory R. (2002). Radiochemistry and nuclear chemistry. Gregory R. Choppin, Jan-Olov Liljenzin, Jan Rydberg (3rd ed.). Woburn, MA: Butterworth-Heinemann. p. 62. ISBN 978-0-08-051566-3. OCLC 182729523.