Ruthenium(III) fluoride
Identifiers
3D model (JSmol)
ChemSpider
  • InChI=1S/3FH.Ru/h3*1H;/q;;;+3/p-3
    Key: YRQNNUGOBNRKKW-UHFFFAOYSA-K
  • F[Ru](F)F
Properties
F3Ru
Molar mass 158.07 g·mol−1
Appearance dark brown solid[1]
Density 5,36 g·cm−3[2]
Melting point 600 °C[2]
insoluble[1]
Related compounds
Other anions
 Ruthenium(III) chloride
Ruthenium(III) bromide
Ruthenium(III) iodide
Other cations
 Rhodium(III) fluoride
Related compounds
 Ruthenium(IV) fluoride
Ruthenium(V) fluoride
Ruthenium(VI) fluoride
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Ruthenium(III) fluoride is a fluoride of ruthenium, with the chemical formula of RuF3.

Preparation

Ruthenium(III) fluoride can be obtained from the reduction of ruthenium(V) fluoride by iodine at 250 °C:[3][4]

Properties

Ruthenium(III) fluoride is a dark brown solid that is insoluble in water. It has a space group of R3c (No. 167).[1][5]

References

  1. ^ a b c R. Blachnik (2013), Taschenbuch für Chemiker und Physiker Band 3: Elemente, anorganische Verbindungen und Materialien, Minerale (in German), Springer-Verlag, p. 700, ISBN 978-3-642-58842-6((citation)): CS1 maint: date and year (link)
  2. ^ a b William M. Haynes (2014), CRC Handbook of Chemistry and Physics (in German), CRC Press, p. 86, ISBN 978-1-4822-0868-9((citation)): CS1 maint: date and year (link)
  3. ^ A. F. Holleman (2019), Lehrbuch der anorganischen Chemie (in German), Walter de Gruyter GmbH & Co KG, p. 1418, ISBN 978-3-11-083817-6((citation)): CS1 maint: date and year (link)
  4. ^ E.A. Seddon, K.R. Seddon (2013), The Chemistry of Ruthenium (in German), Elsevier, p. 155, ISBN 978-1-4832-8990-8((citation)): CS1 maint: date and year (link)
  5. ^ M. A. Hepworth, K. H. Jack u. a.: The crystal structures of the trifluorides of iron, cobalt, ruthenium, rhodium, palladium and iridium. In: Acta Crystallographica. 10, 1957, S. 63, doi:10.1107/S0365110X57000158.
Categories