dimanganese trioxide, manganese sesquioxide, manganic oxide, manganous oxide
3D model (JSmol)
CompTox Dashboard (EPA)
|Molar mass||157.8743 g/mol|
|Appearance||brown or black crystalline|
|Melting point|| 888 °C (1,630 °F; 1,161 K) (alpha form) |
940 °C, decomposes (beta form)
|0.00504 g/100 mL (alpha form) |
0.01065 g/100 mL (beta form)
|Solubility||insoluble in ethanol, acetone |
soluble in acid, ammonium chloride
|Ia3 (No. 206)|
a = 942 pm
Std enthalpy of
|NFPA 704 (fire diamond)|
|manganese trifluoride, manganese(III) acetate|
|chromium(III) oxide, iron(III) oxide|
|manganese(II) oxide, manganese dioxide|
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
what is ?)(
Manganese(III) oxide is a chemical compound with the formula Mn2O3. It occurs in nature as the mineral braunite, and is used in the production of ferrites and thermistors.
Heating MnO2 in air at below 800 °C produces α-Mn2O3 (higher temperatures produce Mn3O4). γ-Mn2O3 can be produced by oxidation followed by dehydration of manganese(II) hydroxide. Many preparations of nano-crystalline Mn2O3 have been reported, for example syntheses involving oxidation of MnII salts or reduction of MnO2.
Manganese(III) oxide is formed by the redox reaction in an alkaline cell:
Manganese(III) oxide Mn2O3 must not be confused with MnOOH manganese(III) oxyhydroxide. Contrary to Mn2O3, MnOOH is a compound that decomposes at about 300 °C to form MnO2.
Mn2O3 is unlike many other transition metal oxides in that it does not adopt the corundum (Al2O3) structure. Two forms are generally recognized, α-Mn2O3 and γ-Mn2O3, although a high pressure form with the CaIrO3 structure has been reported too.
α-Mn2O3 has the cubic bixbyite structure, which is an example of a C-type rare earth sesquioxide (Pearson symbol cI80, space group Ia3, #206). The bixbyite structure has been found to be stabilised by the presence of small amounts of Fe3+, pure Mn2O3 has an orthorhombic structure (Pearson symbol oP24, space group Pbca, #61). α-Mn2O3 undergoes antiferromagnetic transition at 80 K. 
γ-Mn2O3 has a structure related to the spinel structure of Mn3O4 where the oxide ions are cubic close packed. This is similar to the relationship between γ-Fe2O3 and Fe3O4. γ-Mn2O3 is ferrimagnetic with a Néel temperature of 39 K.