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Biofuel is a fuel that is produced over a short time span from biomass, rather than by the very slow natural processes involved in the formation of fossil fuels, such as oil. Biofuel can be produced from plants or from agricultural, domestic or industrial biowaste. The climate change mitigation potential of biofuel varies considerably, from emission levels comparable to fossil fuels in some scenarios to negative emissions in others. Biofuels are mostly used for transportation, but can also be used for heating and electricity.: 173  Biofuels (and bioenergy in general) are regarded as a renewable energy source.: 11
The two most common types of biofuel are bioethanol and biodiesel. The U.S. is the largest producer of bioethanol, while the EU is the largest producer of biodiesel. The energy content in the global production of bioethanol and biodiesel is 2.2 and 1.8 EJ per year, respectively. Demand for aviation biofuel is forecast to increase.
Bioethanol is an alcohol made by fermentation, mostly from carbohydrates produced in sugar or starch crops such as maize, sugarcane, or sweet sorghum. Cellulosic biomass, derived from non-food sources, such as trees and grasses, is also being developed as a feedstock for ethanol production. Ethanol can be used as a fuel for vehicles in its pure form (E100), but it is usually used as a gasoline additive to increase octane ratings and improve vehicle emissions.
Biodiesel is produced from oils or fats using transesterification. It can be used as a fuel for vehicles in its pure form (B100), but it is usually used as a diesel additive to reduce levels of particulates, carbon monoxide, and hydrocarbons from diesel-powered vehicles.
See also: Biomass (energy) § Terminology
The term "biofuel" is used in different ways. One definition is "Biofuels are biobased products, in solid, liquid, or gaseous forms. They are produced from crops or natural products, such as wood, or agricultural residues, such as molasses and bagasse.": 173
Other publications reserve the term biofuel for liquid or gaseous fuels, used for transportation.
First-generation biofuels (also denoted as "conventional biofuels") are made from food crops grown on arable land.: 447 The crop's sugar, starch, or oil content is converted into biodiesel or ethanol, using transesterification, or yeast fermentation.
Main article: Second-generation biofuels
To avoid a "food versus fuel" dilemma, second-generation biofuels (also called advanced biofuels or sustainable biofuels) are made from waste products. These are derived from agriculture and forestry activities such as rice straw, rice husk, wood chips, and sawdust.: 448
The feedstock used to make the fuels either grow on arable land but are byproducts of the main crop, or they are grown on marginal land. Second-generation feedstocks also include straw, bagasse, perennial grasses, jatropha, waste vegetable oil, municipal solid waste and so forth.
The following fuels can be produced using first, second, third or fourth-generation biofuel production procedures. Most of these can be produced using two or three of the different biofuel generation procedures.
Main article: Ethanol fuel
Biologically produced alcohols, most commonly ethanol, and less commonly propanol and butanol, are produced by the action of microorganisms and enzymes through the fermentation of sugars or starches (easiest), or cellulose (which is more difficult).The IEA estimates that ethanol production used 20% of sugar supplies and 13% of corn supplies in 2021. 
Ethanol fuel is the most common biofuel worldwide, particularly in Brazil. Alcohol fuels are produced by fermentation of sugars derived from wheat, corn, sugar beets, sugar cane, molasses and any sugar or starch from which alcoholic beverages such as whiskey, can be made (such as potato and fruit waste, etc.). The ethanol production methods used are enzyme digestion (to release sugars from stored starches), fermentation of the sugars, distillation and drying. The distillation process requires significant energy input for heat (sometimes unsustainable natural gas fossil fuel, but cellulosic biomass such as bagasse, the waste left after sugar cane is pressed to extract its juice, is the most common fuel in Brazil, while pellets, wood chips and also waste heat are more common in Europe) Waste steam fuels ethanol factory – where waste heat from the factories also is used in the district heating grid. Corn-to-ethanol and other food stocks has led to the development of cellulosic ethanol.
Methanol is currently produced from natural gas, a non-renewable fossil fuel. In the future it is hoped to be produced from biomass as biomethanol. This is technically feasible, but the production is currently being postponed for concerns that the economic viability is still pending. The methanol economy is an alternative to the hydrogen economy to be contrasted with today's hydrogen production from natural gas.
9OH) is formed by ABE fermentation (acetone, butanol, ethanol) and experimental modifications of the process show potentially high net energy gains with biobutanol as the only liquid product. Biobutanol is often claimed to provide a direct replacement for gasoline, because it will produce more energy than ethanol and allegedly can be burned "straight" in existing gasoline engines (without modification to the engine or car), and is less corrosive and less water-soluble than ethanol, and could be distributed via existing infrastructures. Escherichia coli strains have also been successfully engineered to produce butanol by modifying their amino acid metabolism. One drawback to butanol production in E. coli remains the high cost of nutrient rich media, however, recent work has demonstrated E. coli can produce butanol with minimal nutritional supplementation. Biobutanol is sometimes called biogasoline, which is not correct, as it is chemically different, being an alcohol, not a hydrocarbon, like biogasoline.
Main article: Biodiesel
Further information: Biodiesel around the world
Biodiesel is the most common biofuel in Europe. It is produced from oils or fats using transesterification and is a liquid similar in composition to fossil/mineral diesel. Chemically, it consists mostly of fatty acid methyl (or ethyl) esters (FAMEs). Feedstocks for biodiesel include animal fats, vegetable oils, soy, rapeseed, jatropha, mahua, mustard, flax, sunflower, palm oil, hemp, field pennycress, Pongamia pinnata and algae. Pure biodiesel (B100, also known as "neat" biodiesel) currently reduces emissions with up to 60% compared to diesel Second generation B100. As of 2020[update], researchers at Australia's CSIRO have been studying safflower oil as an engine lubricant, and researchers at Montana State University's Advanced Fuels Center in the US have been studying the oil's performance in a large diesel engine, with results described as a "game-changer".
Biodiesel can be used in any diesel engine and modified equipment when mixed with mineral diesel. It can also be used in its pure form (B100) in diesel engines, but some maintenance and performance problems may then occur during wintertime utilization, since the fuel becomes somewhat more viscous at lower temperatures, depending on the feedstock used.
Electronically controlled 'common rail' and 'Unit Injector' type systems from the late 1990s onwards may only use biodiesel blended with conventional diesel fuel. These engines have finely metered and atomized multiple-stage injection systems that are very sensitive to the viscosity of the fuel. Many current-generation diesel engines are made so that they can run on B100 without altering the engine itself, although this depends on the fuel rail design. Since biodiesel is an effective solvent and cleans residues deposited by mineral diesel, engine filters may need to be replaced more often, as the biofuel dissolves old deposits in the fuel tank and pipes. It also effectively cleans the engine combustion chamber of carbon deposits, helping to maintain efficiency. In many European countries, a 5% biodiesel blend is widely used and is available at thousands of gas stations. Biodiesel is also an oxygenated fuel, meaning it contains a reduced amount of carbon and higher hydrogen and oxygen content than fossil diesel. This improves the combustion of biodiesel and reduces the particulate emissions from unburnt carbon. However, using pure biodiesel may increase NOx-emissions
Biodiesel is also safe to handle and transport because it is non-toxic and biodegradable, and has a high flash point of about 300 °F (148 °C) compared to petroleum diesel fuel, which has a flash point of 125 °F (52 °C).
In France, biodiesel is incorporated at a rate of 8% in the fuel used by all French diesel vehicles. Avril Group produces under the brand Diester, a fifth of 11 million tons of biodiesel consumed annually by the European Union. It is the leading European producer of biodiesel.
Main article: Biodiesel production
Green diesel is produced through hydrocracking biological oil feedstocks, such as vegetable oils and animal fats. Hydrocracking is a refinery method that uses elevated temperatures and pressure in the presence of a catalyst to break down larger molecules, such as those found in vegetable oils, into shorter hydrocarbon chains used in diesel engines. It may also be called renewable diesel, hydrotreated vegetable oil (HVO fuel) or hydrogen-derived renewable diesel. Unlike biodiesel, green diesel has exactly the same chemical properties as petroleum-based diesel. It does not require new engines, pipelines or infrastructure to distribute and use, but has not been produced at a cost that is competitive with petroleum. Gasoline versions are also being developed. Green diesel is being developed in Louisiana and Singapore by ConocoPhillips, Neste Oil, Valero, Dynamic Fuels, and Honeywell UOP as well as Preem in Gothenburg, Sweden, creating what is known as Evolution Diesel.
Main article: Vegetable oil fuel
Straight unmodified edible vegetable oil is generally not used as fuel, but lower-quality oil has been used for this purpose. Used vegetable oil is increasingly being processed into biodiesel, or (more rarely) cleaned of water and particulates and then used as a fuel. The IEA estimates that biodiesel production used 17% of global vegetable oil supplies in 2021.
Oils and fats reacted with 10 pounds of a short-chain alcohol (usually methanol) in the presence of a catalyst (usually sodium hydroxide [NaOH] can be hydrogenated to give a diesel substitute. The resulting product is a straight-chain hydrocarbon with a high cetane number, low in aromatics and sulfur and does not contain oxygen. Hydrogenated oils can be blended with diesel in all proportions. They have several advantages over biodiesel, including good performance at low temperatures, no storage stability problems and no susceptibility to microbial attack.
Main article: Biogasoline
A study led by Professor Lee Sang-yup at the Korea Advanced Institute of Science and Technology (KAIST) and published in the international science journal Nature used modified E. coli fed with glucose found in plants or other non-food crops to produce biogasoline with the produced enzymes. The enzymes converted the sugar into fatty acids and then turned these into hydrocarbons that were chemically and structurally identical to those found in commercial gasoline fuel.
Bioethers (also referred to as fuel ethers or oxygenated fuels) are cost-effective compounds that act as octane rating enhancers. "Bioethers are produced by the reaction of reactive iso-olefins, such as iso-butylene, with bioethanol."[attribution needed] Bioethers are created from wheat or sugar beets, and also be produced from the waste glycerol that results from the production of biodiesel. They also enhance engine performance, while significantly reducing engine wear and toxic exhaust emissions. Although bioethers are likely to replace ethers produced from petrolium in the UK, it is highly unlikely they will become a fuel in and of itself due to the low energy density. By greatly reducing the amount of ground-level ozone emissions, they contribute to air quality.
When it comes to transportation fuel there are six ether additives: dimethyl ether (DME), diethyl ether (DEE), methyl tert-butyl ether (MTBE), ethyl tert-butyl ether (ETBE), tert-amyl methyl ether (TAME), and tert-amyl ethyl ether (TAEE).
The European Fuel Oxygenates Association identifies MTBE and ETBE as the most commonly used ethers in fuel to replace lead. Ethers were introduced in Europe in the 1970s to replace the highly toxic compound. Although Europeans still use bioether additives, the U.S. Energy Policy Act of 2005 lifted a requirement for reformulated gasoline to include an oxygenate, leading to less MTBE being added to fuel.
An aviation biofuel or bio-jet fuel or bio-aviation fuel (BAF) is a biofuel used to power aircraft and is said to be a sustainable aviation fuel (SAF). The International Air Transport Association (IATA) considers it a key element to reducing the carbon footprint within the environmental impact of aviation. Aviation biofuel could help decarbonize medium- and long-haul air travel generating most emissions, and could extend the life of older aircraft types by lowering their carbon footprint.
Biofuels are biomass-derived fuels from plants or waste; depending on which type of biomass is used, they could lower CO2 emissions by 20–98% compared to conventional jet fuel. The first test flight using blended biofuel was in 2008, and in 2011 blended fuels with 50% biofuels were allowed in commercial flights. In 2019, the IATA was aiming for a 2% penetration by 2025.
Aviation biofuel can be produced from plant sources such as Jatropha, algae, tallows, waste oils, palm oil, Babassu, and Camelina (bio-SPK); from solid biomass using pyrolysis processed with a Fischer–Tropsch process (FT-SPK); with an alcohol-to-jet (ATJ) process from waste fermentation; or from synthetic biology through a solar reactor. Small piston engines can be modified to burn ethanol.Sustainable biofuels do not compete with food crops, prime agricultural land, natural forest or fresh water. They are an alternative to electrofuels. Sustainable aviation fuel is certified as being sustainable by a third-party organisation.
Main article: Biogas
Biogas is methane produced by the process of anaerobic digestion of organic material by anaerobes. It can be produced either from biodegradable waste materials or by the use of energy crops fed into anaerobic digesters to supplement gas yields. The solid byproduct, digestate, can be used as a biofuel or a fertilizer. When CO2 and other impurities are removed from biogas, it is called biomethane.
Biogas can be recovered from mechanical biological treatment waste processing systems. Landfill gas, a less clean form of biogas, is produced in landfills through naturally occurring anaerobic digestion. If it escapes into the atmosphere, it acts as a greenhouse gas.
Farmers can produce biogas from manure from their cattle by using anaerobic digesters.
Main article: Gasification
Syngas, a mixture of carbon monoxide, hydrogen and various hydrocarbons, is produced by partial combustion of biomass, that is, combustion with an amount of oxygen that is not sufficient to convert the biomass completely to carbon dioxide and water. Before partial combustion, the biomass is dried, and sometimes pyrolysed. The resulting gas mixture, syngas, is more efficient than direct combustion of the original biofuel; more of the energy contained in the fuel is extracted.
Syngas may be burned directly in internal combustion engines, turbines or high-temperature fuel cells. The wood gas generator, a wood-fueled gasification reactor, can be connected to an internal combustion engine.
Syngas can be used to produce methanol, dimethyl ether and hydrogen, or converted via the Fischer–Tropsch process to produce a diesel substitute, or a mixture of alcohols that can be blended into gasoline. Gasification normally relies on temperatures greater than 700 °C.
Lower-temperature gasification is desirable when co-producing biochar, but results in syngas polluted with tar.
Main article: Solid fuel § Biomass
The term "biofuels" is also used for solid fuels that are made from biomass, even though this is less common.
Main articles: Algaculture and Algae fuel
Algae can be produced in ponds or tanks on land, and out at sea. Algal fuels have high yields, can be grown with minimal impact on fresh water resources, can be produced using saline water and wastewater, have a high ignition point, and are biodegradable and relatively harmless to the environment if spilled. Production requires large amounts of energy and fertilizer, the produced fuel degrades faster than other biofuels, and it does not flow well in cold temperatures.
By 2017, due to economic considerations, most efforts to produce fuel from algae have been abandoned or changed to other applications.
This class of biofuels includes electrofuels and solar fuels. Electrofuels are made by storing electrical energy in the chemical bonds of liquids and gases. The primary targets are butanol, biodiesel, and hydrogen, but include other alcohols and carbon-containing gases such as methane and butane. A solar fuel is a synthetic chemical fuel produced from solar energy. Light is converted to chemical energy, typically by reducing protons to hydrogen, or carbon dioxide to organic compounds.
Fourth-generation biofuels also include biofuels that are produced by bioengineered organisms i.e. algae and cyanobacteria. Algae and cyanobacteria will use water, carbon dioxide, and solar energy to produce biofuels. This method of biofuel production is still at the research level. The biofuels that are secreted by the bioengineered organisms are expected to have higher photon-to-fuel conversion efficiency, compared to older generations of biofuels. One of the advantages of this class of biofuels is that the cultivation of the organisms that produce the biofuels does not require the use of arable land. The disadvantages include the cost of cultivating the biofuel-producing organisms being very high.
Global biofuel production was 81 Mtoe in 2017 which represented an annual increase of about 3% compared to 2010.: 12 Mtoe stands for Million Tonnes of Oil Equivalent. Furthermore: "the US is the largest producer in the world producing 37 Mtoe in 2017; Brazil and South America, 23 Mtoe; and Europe (mainly Germany) 12 Mtoe".: 12
An assessment from 2017 found that: "Biofuels will never be a major transport fuel as there is just not enough land in the world to grow plants to make biofuel for all vehicles. It can however, be part of an energy mix to take us into a future of renewable energy.": 11
In 2021, worldwide biofuel production provided 4.3% of the world's fuels for transport, including a very small amount of aviation biofuel. By 2027 worldwide biofuel production is expected to supply 5.4% of the world’s fuels for transport including 1% of aviation fuel. The International Energy Agency (IEA) wants biofuels to make up 64% of the world demand for transportation fuels by 2050, in order to reduce dependency on petroleum. However, the production and consumption of biofuels are not on track to meet the IEA's sustainable development scenario. From 2020 to 2030 global biofuel output has to increase by 16% each year to reach IEA's goal.
Further information: Sustainable biofuels
Estimates about the climate impact from biofuels vary widely based on the methodology and exact situation examined.
In general, biofuels emit fewer greenhouse gas emissions when burned in an engine and are generally considered carbon-neutral fuels as the carbon emitted has been captured from the atmosphere by the crops used in production. However, life-cycle assessments of biofuels have shown large emissions associated with the potential land-use change required to produce additional biofuel feedstocks. A review of 179 studies published between 2009 and 2020 found that if no land-use change is involved, first-generation biofuels can—on average—have lower emissions than fossil fuels. However, there is an issue with competition with food. Up to 40% of corn produced in the United States is used to make ethanol, and worldwide 10% of all grain is turned into biofuel. A 50% reduction in grain used for biofuels in the US and Europe would replace all of Ukraine's grain exports. Also, several studies have shown that reductions in emissions from biofuels are achieved at the expense of other impacts, such as acidification, eutrophication, water footprint and biodiversity loss.
The use of second generation biofuels is thought to increase environmental sustainability, since the non-food part of plants is being used to produce second-generation biofuels, instead of being disposed. But the use of this class of biofuels increases the competition for lignocellulosic biomass, increasing the cost of these biofuels.
The indirect land use change impacts of biofuels, also known as ILUC or iLUC (pronounced as i-luck), relates to the unintended consequence of releasing more carbon emissions due to land-use changes around the world induced by the expansion of croplands for ethanol or biodiesel production in response to the increased global demand for biofuels.
As farmers worldwide respond to higher crop prices in order to maintain the global food supply-and-demand balance, pristine lands are cleared to replace the food crops that were diverted elsewhere to biofuels' production. Because natural lands, such as rainforests and grasslands, store carbon in their soil and biomass as plants grow each year, clearance of wilderness for new farms translates to a net increase in greenhouse gas emissions. Due to this off-site change in the carbon stock of the soil and the biomass, indirect land use change has consequences in the greenhouse gas (GHG) balance of a biofuel.Other authors have also argued that indirect land use changes produce other significant social and environmental impacts, affecting biodiversity, water quality, food prices and supply, land tenure, worker migration, and community and cultural stability.
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